Rh nanoparticles have been fabricated by the evaporation method using the He gas in the Rh evaporation chamber, connected with the pre-evacuation chamber of BL6N1 at Aichi Synchrotron Radiation Center (Aichi SR). The electronic and geometric properties of the Rh nanoparticles have been verified without atmosphere exposure (in situ XPS) and after atmosphere exposure (ex situ XPS) using SR-XPS an...

The Rh D antigen is the most clinically important protein blood group antigen of the erythrocyte. It is expressed as a collection of at least 37 different epitopes. The external domains of the Rh D protein involved in epitope presentation have been predicted based on the analysis of variant Rh D protein structures inferred from their cDNA sequences and their D epitope expression. This analysis ...

The contribution of erythropoietin- (EPO) receptors in target tissues, such as bone marrow and spleen, to the nonlinear pharmacokinetics of recombinant human EPO (rh-EPO) was evaluated in rats. The total body clearance after i.v. administration of rh-EPO (0.2-5 microg/kg) decreased as the dose of rh-EPO increased, approaching a plateau at high doses. The uptake clearance of 125I-rh-EPO by the t...

The chemistry of N-substituted amine-boranes and their reactivity towards transition metal centres is well established but the chemistry of B-substituted amine-boranes is not. Here we present the coordination chemistry of H2PhB·NMe3 towards a range of Rh(i) fragments with different P-Rh-P ligand bite angles, {Rh(P(i)Pr3)2}(+), {Rh(P(i)Bu3)2}(+), {Rh((i)Pr2P(CH2)3P(i)Pr2)}(+), {Rh(Ph2P(CH2)nPPh2...

[1] Relative humidity (RH) measurements from Vaisala RS92 radiosondes are widely used in research and operational applications, but their accuracy is not well characterized as a function of height, RH, and time of day (or solar altitude angle). This study compares RS92 RH measurements to simultaneous water vapor measurements from three reference instruments of known accuracy. Cryogenic frost po...

The relative humidity (RH) dependence of aerosol light scattering is an essential parameter for accurate estimation of the direct radiative forcing induced by aerosol particles. Because of insufficient information on aerosol hygroscopicity in climate models, a more detailed parameterization of hygroscopic growth factors and resulting optical properties with respect to location, time, sources, a...

The manuscript reports the synthesis, characterization, and analysis of electronic structure in a series of complexes of small perfluorocarbon ligands with the (PNP)Rh fragment (where PNP is a diarylamido/bis(phosphine) pincer ligand). Reactions of (PNP)Rh(TBE) as the source of (PNP)Rh with CHF3 and C2HF5 produced perfluoroalkylidene complexes (PNP)Rh 0000000000000000000000000000000000 00000000...

The reactivity of the novel family of metalloporphyrin dimers containing a Rh-In bond towards alkyl halides is presented. The chemical reactivity of the homoleptic (same porphyrin ligand) and heteroleptic (different porphyrin ligand) porphyrin complexes with Rh-In metal-metal bond has been examined by photoand thermal-processes in the presence of alkyl halides under anaerobic conditions in the ...