The emission control of NOx in exhaust gases is one of the greatest engineering challenges to extend the practical and commercial application of diesel and lean burn engines. One solution is selective NOx reduction using hydrocarbons in an oxidizing atmosphere. We mainly focused on catalytic reactions under temperature excursion because of the resemblance to conditions prevailing in real automo...

The presence of biogenic or process-derived impurities poses a major problem on the efficient catalytic hydrogenation of biomass-derived levulinic acid to γ-valerolactone; hence, studies on their influence on catalyst stability are now required. Herein, the influence of sulfuric acid as feed impurity on the performance of Ru-based heterogeneous catalysts, including Ru/ZrO2 and mono- and bimetal...

Nanocrystalline ZrO2 (Zirconia) has been synthesized by a conventional precipitation method. The structural, morphological, microstructural, optical and gas-sensing properties of ZrO2 were investigated by using X-ray diffraction analysis (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV-vis spectroscopy and static gas sensing unit, respectively. X-ray diffrac...

The entropy generation based on the second law of thermodynamics is investigated for turbulent forced convection flow of ZrO2-water nanofluid through a square pipe with constant wall heat flux. Effects of different particle concentrations, inlet conditions and particle sizes on entropy generation of ZrO2-water nanofluid are studied. Contributions from frictional and thermal entropy generations ...

For next generation planar lightwave circuit (PLC) devices, high function and high-density integration are required as well as downsizing and cost reduction. To realize these needs, high refractive index difference between a core and a clad (∆) is required. To use PLC for practical applications, silica-based PLC is one of the most attractive candidate. However, degradation of the optical proper...

in this study the effect of nano meter size zro2 particles on the microstructure, densification and hydration resistance of magnesite –dolomite refractories was investigated. 0, 2, 4, 6 and 8 wt. % zro2 particles that were added to magnesite –dolomite refractories containing 35 wt. % cao. the hydration resistance was measured by change in the weight of specimens after 72 h at 25℃ and 95% relati...

The high-k dielectric TiO2/ZrO2 bilayer composite film was prepared on a Si substrate by radio frequency magnetron sputtering and post annealing in N2 at various temperatures in the range of 573 K to 973 K. Transmission electron microscopy observation revealed that the bilayer film fully mixed together and had good interfacial property at 773 K. Metal-oxide-semiconductor capacitors with high-k ...

In recent years many works are aimed at finding a method of controllable switching between hydrophilicity and hydrophobicity of a surface. The hydrophilic surface state is generally determined by its energy. Change in the surface energy can be realized in several different ways. Here we report the ability to control the surface wettability of zirconium dioxide nano-coatings by changing the comp...

An alumina–zirconia composite containing 5 mol% zirconia was prepared by following a wet interaction process in aqueous medium via the sol–gel route. The formed hydrogel which was aged for proper growth and orientation at room temperature, was then dried at a low temperature to minimize agglomeration. The sol–gel derived precursor powder was properly characterized through determination of surfa...

The last decade has witnessed significant improvement in the area of nanofillers on electrical, thermal and mechanical properties of polymeric materials. The dielectric and thermal properties of standard enamel and various nanofiller mixed enamel were detailed and analyzed. Nanopowders of ZrO2, Al2O3 and CNT were used as filler. Ball Mill was used to synthesize nanofillers of ZrO2 and Al2O3. CN...