We report the growth by ion exchange synthesis of ZnS nanoparticles in MCM-41 matrices using Zn (CH3COO)2 and Na2S starting sources. The final product (ZnS/MCM-41) was characterized by X-ray diffraction (XRD) pattern, transmission electron microscopy (TEM), scanning electron microscopy (SEM), infrared spectrometry (IR) and UV-vis spectroscopy. Its crystalline st...

It has been a long time that divergent behaviors were observed in many photocatalytic hydrogen evolution reactions (HER) on CdS and ZnS although the two photocatalysts have similar compositions and structures. For example, CdS itself is inactive and loading of cocatalysts is indispensable to achieve high efficiency of hydrogen evolution, but the reverse is true for ZnS. The underlying reasons a...

This work describes a fast, clean and low-cost approach to synthesize ZnS-PVA nanofluids consisting of ZnS nanoparticles homogeneously distributed in a PVA solution. The ZnS nanoparticles were formed by the electrostatic force between zinc and sulfur ions induced by gamma irradiation at a dose range from 10 to 50 kGy. Several experimental characterizations were conducted to investigate the phys...

Zinc sulfide [ZnS] thin films were deposited on glass substrates using radio frequency magnetron sputtering. The substrate temperature was varied in the range of 100°C to 400°C. The structural and optical properties of ZnS thin films were characterized with X-ray diffraction [XRD], field emission scanning electron microscopy [FESEM], energy dispersive analysis of X-rays and UV-visible transmiss...

Growth time is an important factor in the growth of nanoparticles of a semiconducting material. With this view ZnS is synthesized at different duration of times by chemical method.Nanocrystalline ZnS is synthesized at room temperature by a cost effective chemical reduction method. The dispersed as grown samples in ethanol are characterized using electron diffraction techniques. Simultaneously o...

The theory of tunneling and resonant tunneling is reviewed. Experimental justification of this theory was provided by an InP-based RTD with room-temperature PVR = 12. Its valley current was well-modeled as the sum of thermionic emission through the second resonance and a temperature-independent scattering/defect component. ZnS and CaF2 were experimentally considered as epitaxial barrier materia...

Synthesis of semiconductor nanoparticles with new photophysical properties is an area of special interest. Here, we report synthesis of ZnS nanoparticles in aqueous micellar solution of Cetyltrimethylammonium bromide (CTAB). The size of ZnS nanodispersions in aqueous micellar solution has been calculated using UV-vis spectroscopy, XRD, SAXS, and TEM measurements. The nanoparticles are found to ...

We report the development of a continuous-wave, room-temperature Cr(2+) ZnS laser that is compact and tunable over 700 nm. The laser is pumped by a diode-pumped Er-fiber laser and generates 0.7 W of linearly polarized radiation at 2.35microm , at up to 40% slope efficiency. Cr(2+) ZnS directly diode-pumped at 1.6microm yields polarized radiation that is tunable over 400 nm at up to 25 mW of out...

Different samples of ZnS nanoparticals were synthesized by chemical co-precipitation method at room temperature using zincsulphate as zinc source and sodium sulphide as sulphur source. Structural properties of synthesized ZnS nanoparticles were studied by X-ray diffraction pattern (XRD) while optical properties were examined by UV-Visible absorption spectroscopy. XRD pattern showed the as synth...

A systematic investigation into the excitonic properties of wurtzite ZnS nanowires (NWs) is presented. Under optical excitation, the ZnS NWs exhibit strong ultraviolet (UV) emission. Optical transition from free exciton A, free exciton B, and shallow level emission are observed and analyzed through power-dependent and temperature-dependent photoluminescence spectroscopy measurements performed f...