Hybrid A–B–A type nanowires (NWs) with Ag5Te3–HgTe–Ag5Te3 composition have been created by the reaction of Hg2+ with Ag2Te NWs. The NW morphology of Ag2Te is preserved upon reaction with minor changes and the two separate phases formed are spatially separated within the same NW. The reaction of Hg2+ with Ag2Te NWs was monitored at different concentrations and the reactivity was attributed to ca...

A montmorillonite from Wyoming-USA was used to prepare an organo-clay complex, named 2-thiazoline-2-thiol-hexadecyltrimethylammonium-clay (TZT-HDTA-clay), for the purpose of the selective adsorption of the heavy metals ions and possible use as a chemically modified carbon paste electrode (CMCPE). Adsorption isotherms of Hg2+, Pb2+, Cd2+, Cu2+, and Zn2+ from aqueous solutions as a function of th...

Purpose. To develop a method of using salts humic acids obtained from brown coal Ukraine for sorption heavy metal ions and their extraction ultrafiltration membranes. Methodology. Unique laboratory equipment has been developed to determine the capacity substances with concentration 0 20 mg/l in relation (Cu2+, Pb2+, Cd2+, Hg2+, Zn2+, Co2+) 5 mg/l. The results proximate ultimate analyzes, as wel...

The effect of Zn2+ on t-[3H]butylbicycloorthobenzoate ([3H]TBOB) binding to the GABAA receptor complex was studied autoradiographically in rat brain. Zn2+ inhibited [3H]TBOB binding in a dose-dependent manner at physiological concentrations. Saturation analysis revealed noncompetitive inhibition in various brain regions. The inhibitory effect of Zn2+ had regional heterogeneity; regions showing ...

Cysteine residues are known to perform essential functions within proteins, including binding to various metal ions. In particular, cysteine residues can display high affinity toward zinc ions (Zn2+), and these resulting Zn2+-cysteine complexes are critical mediators of protein structure, catalysis and regulation. Recent advances in both experimental and theoretical platforms have accelerated t...

We demonstrate, for the first time, catalysis by Escherichia coli ribonuclease P (RNase P) RNA with Zn2+ as the sole divalent metal ion cofactor in the presence of ammonium, but not sodium or potassium salts. Hill analysis suggests a role for two or more Zn2+ ions in catalysis. Whereas Zn2+ destabilizes substrate ground state binding to an extent that precludes reliable Kd determination, Co(NH3...

Sustained depolarization of the Xenopus oocyte membrane elicits a slowly activating Na+ current, thought to be due to the opening of sodium selective channels. These channels are induced to become voltage gated by the depolarization. They show unconventional gating properties and are insensitive to tetrodotoxin (TTX). The present study was undertaken to evaluate the effect of extracellular mult...

We report herein a fluoroionophore sensor derivated from tryptophan that shows high sensitivity (detection limit up to 0.15 microM) and specific selectivity for lead ion (Pb2+) over Ca2+, Cd2+, Co2+, Cr3+, Cu2+, K+, Mg2+, Na+, Fe2+, Mn2+, Ni2+ and Zn2+ in aqueous solution.

the disposed wastes of zinc industries contain large amounts of heavy metals such as pb2+ and cd2+. these elements are considered as hazardous elements to human beings and other organisms. this study aims at introducing the fungal isolates that evolved to be compatible with waste deposits during the time and can absorb pb2+ and cd2+ions. during the spring and autumn in 2011, eight samples of se...

Large vesicles (5-15 microns) were formed by hydrating a dried lipid film containing phospholipids labeled with a fluorophore in one fatty acid chain. By using a fluorescence microscope attached to a low-light-intensity charge-coupled-device camera and digital-image processor, the vesicles were easily viewed and initially showed uniform fluorescence intensity across the surface. The fluorescenc...