Zirconium oxy-salts were hydrolyzed to form positively charged polymer or cluster species in acidic solutions. The zirconium hydrolyzed polymer was found to react with a negatively charged polyelectrolyte, such as poly(vinyl sulfate), and to form a stoichiometric polyion complex. Thus, colloidal titration with poly(vinyl sulfate) was applied to measure the zirconium concentration in an acidic s...

o bjectives: providing reliable attachment between bracket base and zirconia surface is a prerequisite for exertion of orthodontic force. the purpose of the present study was to eval- uate the effect of four zirconium surface treatment methods on shear bond strength (sbs) of orthodontic brackets. mat erials and methods: one block of zirconium was trimmed into four zirconium sur- faces, which se...

Authors stressed an importance of low oxygen content of slowly cooled ingots for the homogeneous amorphous half top layers of arc-melted button ingots. The quenching procedure was also not favored to produce amorphous top layers. However authors made a liquid quenching machine to enhance the cooling speed. Photographs Figs.4(b) and 5 are troublesome. Originality as well as scientific significan...

BACKGROUND In vitro analysis has shown that oxidized zirconium on ultra-high molecular weight polyethylene has better wear properties than cobalt-chromium on ultra-high molecular weight polyethylene. The purpose of this study was to determine if oxidized zirconium femoral components performed better than cobalt-chromium in vivo and if the use of oxidized zirconium components had clinical advers...

Reaction of a zinc/zirconium heterobimetallic complex with 1,5-cyclooctadiene (1,5-COD) results in slow isomerization to 1,3-cyclooctadiene (1,3-COD), along with the formation of a new complex that includes a cyclooctyne ligand bridging two metal centers. While analogous magnesium/zirconium and aluminum/zirconium heterobimetallic complexes are competent for the catalytic isomerization of 1,5-CO...

The present study evaluated the shear bond strength between an indirect composite material and zirconium dioxide (zirconia) ceramics after thermocycling. A total of 80 zirconia (Katana) discs were divided into five groups and primed with one of following agents: All Bond 2 Primer B (ABB), Alloy Primer (ALP), AZ Primer (AZP), Estenia Opaque Primer (EOP), and Porcelain Liner M Liquid A (PLA). An ...

Both Zirconium-based alloys and 321stainless steel are widely used as engineering alloys due to their good mechanical properties. Conventional fusion welding techniques for Zr alloys and stainless steel are not feasible due to the formation of brittle intermetallic compounds such as (Zr3Fe, ZrFe2 and Zr2Fe) and corrosion cracking. Brazing is one of the most wide...

Titanium is one of the most utilized metals for orthopedic implants. This element has excellent mechanical and biological properties. As a strategy to develop new system alloys that do not cause health problems patient, such as Ti-6Al-4V alloy, group been designed meet these expectations. Molybdenum, when associated with titanium, reduces transition temperature from α β phase. Zirconium increas...

Treatment of tetrakis(diethylamido)zirconium(IV); [Zr(NEt2)4] with a series of β-ketoimines ({[RHN]C(CH3)=C(H)C(CH3)=O} where R is a functionalized side-chain; 4-(2-methoxyethylamino)pent-3-en-2-one, Hmeap; 4-(3-methoxypropylamino)pent-3-en-2-one, Hmpap; 4-(2-(dimethylamino)ethylamino)pent-3-en-2-one, Hdeap; 4-(3-(dimethylamino)propylamino)pent-3-en-2-one, Hdpap) leads to an amine substitution ...