The development of green, selective, and efficient catalysts, which can aerobically oxidize a variety of alcohols to their corresponding aldehydes and ketones, is of both economic and environmental significance. We report here the synthesis of a novel aerobic oxidation catalyst, a zeolite-confined nanometer-sized RuO(2) (RuO(2)-FAU), by a one-step hydrothermal method. Using the spatial constrai...

The methanol to hydrocarbon process, discovered about 40 years ago, uses zeolites to catalyze the shape selective conversion of methanol to a mixture of hydrocarbons. It has recently gained very much interest, as it allows the conversion of fossil and renewable carbon sources, via synthesis gas and methanol, to a mixture of hydrocarbons. The composition of this hydrocarbon mixture may range fro...

The structure of the as-made, hydrated form of ECR-40C, synthesized in the presence of (2-hydroxyethyl) trimethylammonium (HTMA) ions as an organic structure-directing agent (OSDA) and 2 wt% (relative to alumina in the synthesis mixture) of aluminosilicate zeolite UZM-22 with the MEI topology as seeds, has been determined using synchrotron powder X-ray diffraction and Rietveld analyses. Two dif...

Populations of native fish and aquatic ecosystems have been negatively affected by the contamination of ground and surface waters as a result of various activities. Due to the ferrous chloride (FeCl2), which is used as the reducing agent for the organic synthesis reactions in the contamination of water column and sediment, iron salts may be very toxic for some aquatic organism. In order to mini...

One of the most attractive properties of zeolites are their well organized nanopores and nanochannels which serve readily as supporting hosts for various molecules. Encapsulation of catalytically active transition metal complexes inside the nanopores of zeolites, often referred to as ‘ship-in-a-bottle’ systems,1 has been believed to be one of the most promising strategies in the development of ...

In this paper we report synthesis of Fe2TiO5-5A zeolite (Z5A) nanocomposites with 5%, 10% and 20% weight percent of Fe2TiO5 in 5A zeolite in stearic acid media after calcination of the gel samples obtained at 600-900°C for 2 hrs. The powder X-RAY diffraction (XRD) patterns have been used for characterization of the prepared samples. The Scanning Electron Microscopy (SEM) images and X-ray Energy...

Immobilization of photocatalysts in porous materials is an approach to significantly minimize the hazards manipulation and recovery nanoparticles. Inorganic materials, such as zeolites, are proposed promising for photocatalyst immobilization mainly due their photochemical stability. In this work, a green synthesis method combine TiO2-based with commercial ZY zeolite. Moreover, preliminary analy...

We report an original and scalable synthesis pathway to produce encapsulated gold nanoparticles. Precise control of the gold particles is achieved in the range of 1-10 nm through the impregnation of silicalite-1 with a controlled concentration of gold solution, followed by dissolution-recrystallization of the zeolite.

We report the one-step synthesis of a highly active hierarchical Fe/ZSM-5 zeolite catalyst with a strongly improved lifetime in the selective hydroxylation of benzene to phenol with nitrous oxide; compared to the best Fe/ZSM-5 catalyst, the turnover number after 24 h on stream is almost four times higher.

Zeolite Y, as a solid acid catalyst with excellent performance, is landmark in petroleum refining and chemical industry production–especially catalytic cracking reactions. Improving the SAR of Y zeolite, enriching its pore structure, modifying it heteroatoms can realize multifunctional catalysis improve application value it, then meet demands refining. In this review, synthesis zeolites high SA...