The uptake of H2SO4 and CH3SO3H onto particles composed of water and sulfuric acid was studied in a laminar flow reactor at atmospheric pressure. Their first-order gas-phase loss rate coefficients were determined using a chemical ionization mass spectrometer. Relative humidity was varied from 6% to 97% at 295-297.5 K. The mass accommodation coefficient, alpha, was found to be close to unity for...

The corrosion inhibition of mild steel in 1M H2SO4 by polyvinyl pyrrolidone (PVP) and the synergistic effect of iodide ions were investigated using weight loss and hydrogen evolution methods in the temperature range of 30 – 60 o C. The corrosion rates of mild steel decreased with the increasing concentration of PVP, while the inhibition efficiency (%I) increased. The inhibition efficiency of PV...

South African discard coal fines and K2CO3 blends were heated in a laboratory-scale rotary kiln to produce ashes for H2SO4 leaching tests. The optimized conditions of 6.12 mol.dm3 (M) H2SO4, solid liquid ratios 1:5 1:10, 8o°C 8 hours used. was added increase the dissolution efficiency K. objective determine if Al present metakaolinite (Al2O3.2SiO2), Al, K, Ti alumino-silicate glasses, rutile (T...

The methyl, ethyl, propyl and butyl esters of the fatty acids of Thevetia peruviana seed oil were successfully prepared by the batch-esterification procedures. Various acid catalyst and various molar ratios of fatty acid to alcohol were investigated. H3PO4 was found to be ineffective to catalyze the esterification of the free fatty acid. HCl gas and conc. H2SO4 both proved very effective in cat...

Discs of polyvinyl alcohol cross-linked with glutaraldehyde were synthesized under acid catalysis (H2SO4). Then, the antigen F1 purified from Yersinia pestis was covalently linked to this modified polymer. Afterwards, an enzyme-linked immunosorbent assay (ELISA) was established for the diagnosis of plague in rabbit and human. The best conditions for the method were achieved by using 1.3 microgr...

Sulfate complexation of lanthanides is of great interest for predicting speciation of radionuclides in natural environments. The formation of LaSO4+(aq) in HNO3/H2SO4 aqueous solutions of low ionic strength (I) was studied by nanoelectrospray ionization mass spectrometry (nanoESI-MS). Several gaseous species containing LaSO4+ were detected. The formation constant of LaSO4+(aq) was determined an...

The corrosion inhibition potential and efficacy of 2-hydropyrimidine-2-thione derivative on mildsteel in 0.5 M sulfuric acid solution was investigated using electrochemical polarization and FTIRspectroscopic techniques. In addition, docking studies were carried out as theoretical investigationof adsorption inhibitor on iron surface. The results of polarization studies indicate...

The uptake of methanol at the air-liquid interface of 0-96.5 wt % sulfuric acid (H2SO4) solutions has been observed directly using vibrational sum frequency generation (VSFG) spectroscopy. As the concentration of H2SO4 increases, the VSFG spectra reveal a surface reaction between methanol and H2SO4 to form methyl hydrogen sulfate. The surface is saturated with the methyl species after 15 min. T...

An Al8Co19Cr23Fe32Ni18 high-entropy alloy with a solid solution of Al was prepared, and its pitting corrosion resistance in 0.1 M NaCl high-temperature oxidation at 1273 K were assessed. The potential this is lower than that the Al-free Co19Cr23Fe40Ni18 alloy, although higher. decrease owing to addition attributed surface oxide film nitride inclusions metal matrix. For potentiodynamic polarizat...