background: development of safe radioprotector is a challenging task. in this study radioprotective effect of sucrose has been demonstrated in calf thymus dna (ctdna). sucrose is a free radical scavenger and also acts as osmolyte and therefore can influence the water activity around dna and effects of radiation on dna. hoechst 33258 was used to probe the possible alteration in physicochemical p...

The "dynamic" or "glass" transition in biomolecules is as important to their functioning as the folding process. This transition occurs in the low temperature regime and has been related to the onset of biochemical activity that is dependent on the hydration level. This protein transition is believed to be triggered by the strong hydrogen bond coupling in the hydration water. We study the vibra...

0009-2614/$ see front matter 2011 Elsevier B.V. A doi:10.1016/j.cplett.2011.03.013 ⇑ Corresponding author at: Departamento de Quími Ciências, Universidade de Lisboa, 1749-016 Lisboa, Po E-mail address: [email protected] (B.J.C. Cabral). Electronic properties of a methane–water solution were investigated by a sequential quantum mechanical/molecular dynamics approach. Upon hydration methane acquir...

The varying states of water confined in the nano-domain structures of typical room temperature ionic liquids (ILs) were investigated by (1)H NMR and by measurements of self-diffusion coefficients while systematically varying the IL cations and anions. The NMR peaks for water in BF4-based ILs were clearly split, indicating the presence of two discrete states of confined water (H2O and HOD). Prot...

We study the relaxation times tα in the water-methanol system. We examine new data and data from the literature in the large temperature range 163 < T < 335 K obtained using different experimental techniques and focus on how tα affects the hydrogen bond structure of the system and the hydrophobicity of the alcohol methyl group. We examine the relaxation times at a fixed temperature as a functio...

The dielectric properties of two low-water-content tissues, bone marrow and adipose tissue, were measured from 1 kHz to 1 GHz. From 1 kHz to 13 MHz, the measurements were performed using a parallel-plate capacitor method. From 10 MHz to 1 GHz, a reflection coefficient technique using an open-ended coaxial transmission line was employed. The tissue water contents ranged from 1 to almost 70% by w...

This article presents an overview of recent experiments performed on transport properties of water in the deeply supercooled region, a temperature region of fundamental importance in the science of water. We report data of nuclear magnetic resonance, quasi-elastic neutron scattering, Fourier-transform infrared spectroscopy, and Raman spectroscopy, studying water confined in nanometer-scale envi...

the effects of zinc oxide nanorod (zno-n) incorporation on thephysicochemical properties of tapioca starch / bovin gelatin composite film such as water absorption capacity (wаc), water solubility and permeability to water vapour (wvp) were investigated. in this search, zno-n was homogenized by sonication and added into tapioca starch / bovine gelаtin dispersions аt different concentrations (e.g...

in this work, we studied the effect of carboxylic acid on the rheological properties of a high-alumina cement mortar (ch45) produced by the algerian firm refractal.the investigated properties are setting time, water consumption, electrical conductivity, ph, density and the compressive strength. the results show a setting time of about 200 min for the acid free, 180 min with 0.1 % of carboxylic ...