This paper reports the syntheses, crystal structures and magnetic properties of Mn(III) hexadentate Schiff base complexes [Mn(4-OH-sal-N-1,5,8,12)]NO3(1) [Mn(4-OH-sal-N-1,5,8,12)]ClO4(2), where (4-OH-sal-N-1,5,8,12)2? (4,4?-((1E,13E)-2,6,9,13-tetraazatetradeca-1,13-diene-1,14-diyl)bis(3-methoxyphenol) is a new hydroxyl-substituted ligand. The introduction ligand induces more hydrogen bonding in...

The Front Cover image is provided by the Ikeshita and Tsuno group at Nihon University (Japan), together with Imai Kindai (Japan). depicts three chiral bis(boron difluoride) complexes whose circularly polarized luminescence (CPL) properties were studied in this work. reflect off sea surface, reminiscent of mirror CPL spectra obtained study, similar to reflection islands background image. Read fu...

A dicompartmental Schiff base ligand was synthesized and used for the assembly of a lanthanide grid-like complex. Dinuclear Dy2 tetranuclear Dy4 complexes were isolated from reaction with different dysprosium salt. Single crystal X-ray diffractions show that two DyIII ions in are adopted N3O coordination pockets further coordinated by water molecules, whereas, Dy4, four clamped ligands through ...

In this article, we submit the description of synthesis and identification of manganese(II) complexes with pyrogenic nanosilica-immobilized (d av = 10 nm; S sp = 290 m(2)/g) hydroxyaldimine ligands [Formula: see text]: salicilaldiminopropyl (L1); 5-bromosalicilaldiminopropyl (L2); 2-hydroxynaphtaldiminopropyl (L3); 2-hydroxy-3-methoxybenzaldiminopropyl (L4); 2-hydroxy-3,5-dichloroacetophenonimi...

A dinuclear zinc complex [Zn2L2] (1), and four mononuclear complexes [ZnBr2(LH)2] (2), [ZnCl2(LH)2] (3), [Zn(LH)2(NCS)2] (4) [ZnI(CH3OH)L] (5), have been prepared from the Schiff base 5-bromo-2-((cyclohexylimino) methyl)phenol (HL) by microwave irradiation method. All were characterized CHN elemental analyses, infrared electronic spectra. Structures of further studied single crystal X-ray deter...