The mechanism for the diffusion of vinyl bromide (VB) through the nonporous van der Waals organic solid of p-tert-butylcalix[4]arene (tBC) is examined by molecular mechanics calculations. In a "squeeze" mechanism, a VB molecule passes through the interstitial space in the rim regions of tBC bowls, after the partial filling of nearby inclusion sites, and couples with the both the rotation of but...

BACKGROUND Classic self-curing temporary cements obstruct the translucence of provisional restorations. New dual-cure esthetic temporary cements need investigation and comparison with classic cements to ensure that they are equally retentive and provide adequate translucence. The objective is to analyze by means of traction testing in a in vitro study the retention of five temporary cements. ...

By combining a newly established single-cell cytotoxicity assay in agarose (16) with estimations of the maximum natural killer (NK) potential (Vmax) by 51Cr release that percentage of target-binding cells (TBC), the fraction of active killers among TBC, the kinetics of single-cell cytotoxicity, and the recycling of effector cells was studied. Using nylon wool-passed peripheral lymphocytes, appr...

Micromechanical models are developed to explore the effect of embedded metal layers upon thermal cycling delamination failure of thermal barrier coatings (TBCs) driven by thickening of a thermally grown oxide (TGO). The effects of reductions in the steady-state (i.e. maximum) energy release rate (ERR) controlling debonding from large interface flaws and decreases in the thickening kinetics of T...

The Teacher Behavior Checklist (TBC) is an internationally recognized instrument to conduct formative assessment for teachers. TBC has been specifically adapted Brazilian undergraduates ensure that its psychometric properties are satisfactory this target population. However, it not clear whether the two-factor model adequate and what extent different degrees of teacher performance detected by u...

O objetivo do trabalho é analisar os modelos de negócios com impacto social e o Turismo Base Comunitária (TBC) no contexto Bonito/MS. estudo possui características exploratórias, descritivas, abordagem qualitativa. Foram identificados dois negócios: Instituto Família Legal Visão Vida. Para a pesquisa foram utilizadas entrevistas dados tratados considerando análise conteúdo. atributos que qualif...

Owing to its high penetrability with dielectric materials, terahertz time domain spectroscopy (THz-TDS) is a promising nondestructive measurement technology. The coating thickness deviation and defect of thermal barrier coatings (TBC) will affect insulation performance lifetime. In this work, THz-TDS was applied measure the distribution TBC. refractive index obtained by transmission mode. To av...

introduction: the aim of the present study was to investigate the effects of srp assisted by the two clinical treatment methods of diode laser or chlorhexidine gel applications in comparison with srp alone. methods: eight patients with moderate to severe chronic periodontitis, each with at least three pockets 4–7 mm deep, were selected for this study. over 66 pockets were selected and randomly ...

Electron beam (EB) physical vapour deposited (PVD) thermal barrier coatings (TBCs) have been used in gas turbine engines for a number of years. The primary mode of failure is attributed to oxidation of the bondcoat and growth of the thermally grown oxide (TGO), the alumina scale that forms on the bondcoat and to which the ceramic top coat adheres. Once the TGO reaches a critical thickness the T...

Thermal barrier coating systems are used on top of highly stressed components in gas turbines to protect the nickel-based substrates. A well-established thermal barrier coating system consist of the bond-coat (BC) and the thermal barrier coating (TBC). A third layer is grown during service: the thermally grown oxide (TGO) between the BC and the TBC. The coatings fail in service because of diffe...