Nine new mononuclear and polynuclear Cu(II) complexes [Cu(H2L )Cl]Cl·3H2O (1), [Cu(H2L )Cl]Cl·H2O (2), [Cu(H2L )Cl]Cl·2.5H2O (3), [Cu3(μ -L)2(H2O)3](ClO4)2·H2O (4), [Cu4(μ-HL )4](ClO4)8·CH3OH·5H2O (5), [Cu2(HL )2](ClO4)2·2H2O (6a), [Cu2(μ-HL )2](ClO4)2·H2O (6b), [Cu2(μ-HL )(L)Cu(teta)](ClO4)3·2H2O (7) and [Cu2(H2L )2(ox)](ClO4)2·2H2O·2MeOH (8) containing [5-(2-pyridine-2-yl)-1,2,4-triazole-3-yl...

BACKGROUND Intracellular calcium (Ca²⁺) coordinates the cardiac contraction cycle and is dysregulated in diabetic cardiomyopathy. Treatment with triethylenetetramine (TETA), a divalent-copper-selective chelator, improves cardiac structure and function in patients and rats with diabetic cardiomyopathy, but the molecular basis of this action is uncertain. Here, we used TETA to probe potential lin...

Abstract The influence of branched N , ′-bis( p -hydroxybenzoyl) containing propylenediamine (PDA) and triethylenetetramine (TETA) composites for corrosion inhibition carbon steel in acidic solution (1 M HCl) was investigated using several quantum chemical, electrochemical impedance spectroscopy potentiodynamic polarization as techniques. molecules were posteriorly characterized by proton nucle...

Nine new mononuclear and polynuclear Cu(II) complexes [Cu(H2L(2))Cl]Cl·3H2O (1), [Cu(H2L(3))Cl]Cl·H2O (2), [Cu(H2L(4))Cl]Cl·2.5H2O (3), [Cu3(μ(3)-L(1))2(H2O)3](ClO4)2·H2O (4), [Cu4(μ-HL(1))4](ClO4)8·CH3OH·5H2O (5), [Cu2(HL(3))2](ClO4)2·2H2O (6a), [Cu2(μ-HL(3))2](ClO4)2·H2O (6b), [Cu2(μ-HL(3))(L(3))Cu(teta)](ClO4)3·2H2O (7) and [Cu2(H2L(3))2(ox)](ClO4)2·2H2O·2MeOH (8) containing [5-(2-pyridine-2...

Currently, approximately 70-80 % of casting production of ferrous alloys is done with sands containing bentonite (green sands). Information on an amount of active bentonite in moulding sands, after shakeout of casting, is necessary in the rebounding process of bentonite sands – under real casting house conditions. It decides how much of fresh bentonite should be added to moulding sands, thereby...

Stable coinage metal nanoparticles (NPs) have been synthesized individually in an aqueous alkaline solution from the corresponding metal salts as precursors using the condensation product (CP) of salicylaldehyde and triethylenetetramine as a reagent. Silver and gold NPs are obtained with and without light illumination but UV irradiation is essential for Cu(0)NP formation. During nanoparticle fo...

A series of new manganese thioarsenates(V) [Mn(en)2Cu(AsVS4)]n (1, en = ethylenediamine), [Mn(dien)2][Mn(dien)(AsVS4)]2 (2, dien = diethylenetriamine), [Mn(teta)(AsVS4)]n (3, teta = triethylenetetramine), and {[Mn(dap)2][Mn(dap)(AsVS4)]2}n (4, dap = 1,2-diaminopropane) have been solvothermally synthesized and structurally characterized. 1 displays a neutral heterometallic [Mn(en)2Cu(AsVS4)]n ch...