The non-thermal effects of microwave irradiation on enzyme-catalyzed reactions have been evaluated by keeping the reaction temperature constant during irradiation. Subtilisin-catalyzed transesterification and a-chymotrypsin-catalyzed esterification have been carried out in six solvents of differing polarities and at three different temperatures. In all cases, microwave irradiation was found to ...

This paper deals with the effect of water and catalyst (KOH) amount on the quantity and quality of transesterification products of rapeseed oil by methanol, the methyl ester phase (i.e. yield, conversion), and the side-product, the glycerol phase (i.e. density, viscosity, the mass fraction of glycerol, esters, soaps). The dependencies were described by statistical models. The transesterificatio...

Transesterification is one of the most popular methods to decrease the viscosity of vegetable oils to produce biodiesel. It is the reaction of vegetable oil/ fats with an alcohol to give fatty acid alkyl esters in the presence of a catalyst with glycerol as by product. A catalyst is used to increase the rate of reaction and yield. The reaction is very much affected by the free fatty acids conte...

The feedstock used in our experiment for the production of biodiesel was Yellow Grease. The whole experiment was divided into two parts: Production and Testing. Production involves Transesterification of free fatty acids in yellow grease to form yellow grease alkyl esters. The process of testing involved calculation of the physio – chemical properties, acid value, density, kinematics viscosity ...

this study is concerned with the viability of producing biodiesel from waste beef bone fat and evaluate this product according to the quality requirements defined by astm d- 6751. accordingly, beef bone fat was heated to remove the moisture under vacuum at 60 . alkaline catalysed transesterfication was carried out by  using 6:1 molar ratio of ethanol to fat in the presence of 1% w/w sodium hydr...

Transesterification reaction of vegetable oil with ethanol leads to ethyl esters, used to date for applications principally in food and cosmetic industry. To open the application field to biofuels (to substitute current fuels resulting from fossil resources), the process efficiency has to be developed to be economically profitable. In this work, the sunflower oil ethanolysis was performed in a ...

in the present study, the kinetics of biodiesel production through transesterification of brassica carinata oil with methanol in the presence of potassium hydroxide is investigated by kinetic monte carlo simulation. the obtained results from simulation agree qualitatively with the existing experimental data. the kinetics data for each step of suggested mechanism are confirmed by simulation. by ...

Leevijit, T., Wisutmethangoon, W., Prateepchaikul, G., Tongurai, C., Allen, M. Design and test of a continuous reactor for palm oil transesterification Songklanakarin J. Sci. Technol., 2006, 28(4) : 791-802 The continuous reactor for transesterification of refined palm oil with methanol was designed and tested. The reaction condition was focused at ambient pressure, temperature of 60oC, molar r...

0016-2361/$ see front matter 2011 Elsevier Ltd. A doi:10.1016/j.fuel.2011.03.042 Abbreviations: CFME, chicken fat methyl esters; American society of testing and materials; KOH, p sodium hydroxide; KOMe, potassium methoxide; NaO ⇑ Corresponding author at: Department of Automo Kocaeli University, 41380 Kocaeli, Turkey Tel.: +90 3032203. E-mail addresses: [email protected], Canakci). In t...

This study is concerned with the viability of producing biodiesel from waste beef bone fat and evaluate this product according to the quality requirements defined by ASTM D- 6751. Accordingly, beef bone fat was heated to remove the moisture under vacuum at 60 . Alkaline Catalysed Transesterfication was carried out by  using 6:1 molar ratio of ethanol to fat in the presence of 1% w/w sodium hydr...