Recently J.C. Rohde constructed families of Calabi-Yau threefolds parametrised by Shimura varieties. The points corresponding to threefolds with CM are dense in the Shimura variety and, moreover, the families do not have boundary points with maximal unipotent monodromy. Both aspects are of interest for Mirror Symmetry. In this paper we discuss one of Rohde’s examples in detail and we explicitly...

Gromov-Witten theory is used to define an enumerative geometry of curves in Calabi-Yau 4-folds. The main technique is to find exact solutions to moving multiple cover integrals. The resulting invariants are analogous to the BPS counts of Gopakumar and Vafa for Calabi-Yau 3-folds. We conjecture the 4-fold invariants to be integers and expect a sheaf theoretic explanation. Several local Calabi-Ya...

It is known that many Calabi-Yau manifolds form a connected web. The question of whether all Calabi–Yau manifolds form a single web depends on the degree of singularity that is permitted for the varieties that connect the distinct families of smooth manifolds. If only conifolds are allowed then, since shrinking two-spheres and three-spheres to points cannot affect the fundamental group, manifol...

Peptidyl prolyl cis-trans isomerases (PPIases) are ubiquitous enzymes in biology that catalyze the cis-trans isomerization of the proline imide peptide bond in many cell signaling pathways. The local change of the isomeric state of the prolyl peptide bond acts as a switching mechanism in altering the conformation of proteins. A complete understanding of the mechanism of PPIases is still lacking...

Ligand 2-diphenylphosphinothiophenol (Hsarp) reacted with Pt(PPh3)4 to yield trans-[PtH(sarp)(PPh3)], which undergoes fast exchange with free PPh3 on the NMR time scale and very slowly and reversibly formed some cis-[PtH(sarp)(PPh3)] over time in solution (11%, 24 h). Reaction of trans-[PtH(sarp)(PPh3)] with Hsarp in boiling toluene gave cis- and trans-[Pt(sarp)2]; the cis isomer being more sta...

In an attempt to identify the structure of a sesquiterpene from Cistus creticus ssp. creticus proposed in the literature as 1,1,4a,6-tetramethyl-5-methylene-1,2,3,4,4alpha,5,8,8alpha-octahydronaphthalene, the synthesis of its cis isomer 2 was carried out in 11 steps and 9.5% yield. Comparison of the spectra of 2 and those reported earlier for the synthetic trans isomer 1 with the spectral profi...

The common practice in North American feedlot industries is to add antibiotics to the diet to prevent disease and improve both BW gain and feed efficiency. In this study, 240 crossbred steer calves were backgrounded on a 54% silage diet for 80 d and fed a finishing diet consisting of 81% barley grain, 10% barley silage, and 7.5% supplement (DM basis) with and without in-feed antibiotics for app...

Photochemical and photocatalytic degradation of the emerging pollutant trans-resveratrol has been studied under different irradiation wavelengths and using different TiO2 catalysts. trans-Resveratrol was more easily degraded when irradiated using the whole spectral range (UV-Vis) rather than with UV and near-UV to visible irradiation. The main intermediate of trans-resveratrol phototransformati...

On the basis of the isomer-specific effects of trans fatty acids (FA) on human health, and the detrimental effect of t10,c12-conjugated linoleic acid (CLA) on cows' milk fat production, there is a need to identify factors that affect the shift from trans-11 to trans-10 pathway during ruminal biohydrogenation of FA. This experiment was conducted in vitro and aimed at separating the effects of th...

This study was carried out to investigate the effect of different cooking techniques applied meats on total CLAs, cis-9,trans-11-CLA (c9,t11-CLA) and trans-10,cis-12-CLA (t10,c12-CLA). . In study, four methods such as boiling, frying, baking grilling were meat samples taken from bovine carcasses. raw cooked samples, CLA, cis-9, trans-11 trans-10, cis-12 isomer amounts examined in Gas Chromatogr...