Eight titanium complex greases (i.e., benzoic acid/stearic acid and sebacic acid/stearic acid titanium complex greases, and greases containing PTFE, or nanotitanium dioxide, or nano-silicon dioxide) were synthesized using 3-L reaction vessel. Their physical characteristics were characterized and their tribological properties were evaluated by using a four-ball tester. Chemical compositions of t...

The liquid-phase photocatalytic oxidation of l-octanol in oxygenated acetoniaile on highly dispersed titanium oxide catalysts anchored onto transparent Vycor glass was compared with that obtained on the standard TiO2 powder. The isolated titanium oxide species anchored onto transparent Vycor glass are responsible for its high photocatalytic activity both in the present liquid-phase oxidation of...

Nb, Ta, and Zr are the favorable nontoxic and allergy-free alloying elements suitable for use in titanium alloys for biomedical applications. Low-rigidity titanium alloys composed of nontoxic and allergy-free elements are receiving considerable attention. The advantage of low-rigidity titanium alloys in the healing of bone fracture and bone remodeling is successfully proven by using tibia of ra...

The aim of this study was to examine the effect of NaOCl pretreatment on the biomechanical fixation of implant at the early healing stage of a rat model. Polished titanium cylindrical implants and disks were prepared, and one-half of these samples were dual acidetched. Then, one-half of both surfaces were chemically-cleaned by pretreatment with 5% NaOCl solution for 24 h. Morphological analyses...

A retrospective review of 21 patients that underwent bone screw removal from the elbow was studied in relation to the type of metal, duration of implantation, and the location of the screws about the elbow. Screw failure during extraction was the dependent variable. Five of 21 patients experienced hardware failure during extraction. Fourteen patients had titanium alloy implants. In four cases, ...

Complexation reactions of titanium tetraethoxide [Ti(OEt)4] and titanium tetra-n-butoxide [Ti(OBu )4] with 3-pentenoic acid (PA) and allylacetoacetate (AAA), in a 1 : 1M ratio, were studied in ethanol solution at room temperature. C-NMR and FTIR spectra showed that all PA and AAA completely reacted with both titanium alkoxides. Hydridosilane compounds such as triethoxysilane and triethylsilane ...

This study evaluated the feasibility of using three-dimensional printing (3DP) to fabricate porous titanium implants. Titanium powder was blended with a water-soluble binder material. Green, porous, titanium implants fabricated by 3DP were sintered under protective argon atmosphere at 1,200, 1,300, or 1,400°C. Sintered implant prototypes had uniform shrinkage and no obvious shape distortion aft...

The objective of this study is to investigate the effect of cyclic precalcification treatment to impart bioactive properties for titanium implants. Before precalcification, the titanium implants were subjected to blasting using hydroxyapatite (HAp), a resorbable blasting medium (RBM treated), and anodized using an electrolyte containing glycerol, H2O, and NH4F. Precalcification treatment was pe...

Recent accreditation of titanium powder products for commercial aircraft applications marks a milestone in titanium powder metallurgy. Currently, powder metallurgical titanium production primarily relies on vacuum sintering. This work reported on the feasibility of powder sintering in a non-vacuum furnace and the tensile properties of the as-sintered Ti. Specifically, we investigated atmospheri...

Biocompatibility improvements for blood contacting materials are of increasing interest for implanted devices and interventional tools. The current study focuses on inorganic (titanium, titanium nitride, titanium oxide) as well as diamond-like carbon (DLC) coating materials on polymer surfaces (thermoplastic polyurethane), deposited by magnetron sputtering und pulsed laser deposition at room te...