نتایج جستجو برای: thermolysis

تعداد نتایج: 643  

2008

The present invention provides methods for the thermolysis of lignocellulosic materials, such as wood, cellulose, lignin, and lignocellulose. In specific embodiments, the methods comprise combining the lignocellulosic material with an ionic liquid and subjecting the mixture of the lignocellulosic material and the ionic media to pyrolytic conditions to form a recoverable product, such as a commo...

2015
Maninder Singh Masanobu Miyata Shunsuke Nishino Derrick Mott Mikio Koyano Shinya Maenosono

In this report, copper iron sulfide nanoparticles with various composition were synthesized by a thermolysis based wet chemical method. These inherently sustainable nanoparticles were then fully characterized in terms of composition, structure, and morphology, as well as for suitability as a thermoelectric material. The merits of the material preparation include a straightforward bulk material ...

Journal: :The journal of physical chemistry. B 2005
Sang-Hyun Choi Eung-Gyu Kim Jongnam Park Kwangjin An Nohyun Lee Sung Chul Kim Taeghwan Hyeon

We report the large-scale synthesis of uniform-sized hexagonal pyramid-shaped ZnO nanocrystals by the thermolysis of Zn-oleate complex, which was prepared from the reaction of inexpensive and environmentally friendly reagents such as zinc chloride and sodium oleate. Under optimized reaction conditions, we were able to synthesize as much as 2.83 g using 300 mL of oleylamine and 90 mL (284 mmol) ...

2001
Pradeep Mathur Sarbani Mukhopadhyay Moawia O. Ahmed Goutam K. Lahiri Soma Chakraborty Vedavati G. Puranik Mohan M. Bhadbhade Shubhangi B. Umbarkar

Thermolysis of a toluene solution containing [Fe2W(CO)10( 3-S)2] (1) and [( -C5H5)W(CO)3(CCPh)] (2), at 80°C yields the mixed metal cluster [Fe2(CO)6( 3-S)2W{( -C5H5)W(CO)3(CCPh)}2] (3). Structure of 3 has been established crystallographically. It consists of a triangular Fe2W unit, each face of which is capped by a sulfido ligand. Each Fe atom bears three carbonyl groups. Two separate molecule...

2002
E. Huang M. F. Toney W. Volksen D. Mecerreyes P. Brock H.-C. Kim C. J. Hawker J. L. Hedrick V. Y. Lee R. D. Miller L. B. Lurio

Small angle x-ray scattering ~SAXS! measurements were performed on nanoporous methyl silsesquioxane films that were generated by the incorporation of a sacrificial polymeric component into the matrix and subsequently removed by thermolysis. The average pore radii ranged from 1 to 5 nm over a porosity range of ;5–50%. The distribution in pore size was relatively broad and increases in breadth wi...

Journal: :Chemical communications 2011
Ai Ling Tan Alexander J Blake E Stephen Davies Claire Wilson C David Garner

A new method has been developed to synthesise bis η(5)-cyclopentadienyl dithiolene complexes of molybdenum and tungsten. This procedure involves the in situ thermolysis of the azo compounds, 2,2'-azobisisobutyronitrile (AIBN) or 1,1'-azobiscyclohexanecarbonitrile (ACCN) (R'(2)N(2), R' = CMe(2)CN or C(6)H(10)CN, respectively), which initiates a reaction between [Cp(2)M(S(4))] (M = Mo or W) and a...

2018
Thaís A Rossa Nícolas S Suveges Marcus M Sá David Cantillo C Oliver Kappe

An efficient three-step protocol was developed to produce 2-(azidomethyl)oxazoles from vinyl azides in a continuous-flow process. The general synthetic strategy involves a thermolysis of vinyl azides to generate azirines, which react with bromoacetyl bromide to provide 2-(bromomethyl)oxazoles. The latter compounds are versatile building blocks for nucleophilic displacement reactions as demonstr...

2004
Guan-Wu Wang Yu-Jin Li Ru-Fang Peng Zhen-Hua Liang You-Cheng Liu

[60]Fullerene-fused pyrazolines 1 were prepared by the reaction of C60 with alky diazoacetates under the solid-state high-speed vibration milling conditions as well as in toluene solution. Pyrazolines 1 were stable in refluxing toluene and its thermolysis process in 1,2-dichlorobenzene was investigated, the decomposition rates and activation energies of pyrazolines 1 were obtained. The current ...

Journal: :Dalton transactions 2011
Nikolaos Tsoureas Joshua Nunn Thomas Bevis Mairi F Haddow Alex Hamilton Gareth R Owen

The complexes [Ru(Tai)Cl{=C(H)Ph}(PCy(3))] (4) and [Ru((Ph)Bai)Cl{=C(H)Ph}(PCy(3))] (5) [where Tai = HB(7-azaindolyl)(3) and (Ph)Bai = Ph(H)B(7-azaindolyl)(2)] have been prepared and structurally characterised. The borohydride unit is located in the coordination site trans to the chloride ligand in both complexes. The degree of interaction between the borohydride group and the metal centre was ...

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