نتایج جستجو برای: thermodynamic approach
تعداد نتایج: 1326438 فیلتر نتایج به سال:
In the previous multi-solid models,φ approach is used for the calculation of fugacity in the liquid phase. For the first time, in the proposed multi-solid thermodynamic model,γ approach has been used for calculation of fugacity in the liquid mixture. Therefore, some activity coefficient models have been studied that the results show that the predictive Wilson model is more appropriate than othe...
Data-driven stochastic and probabilistic methods that underlie reliability prediction and structural integrity assessment remain unchanged for decades. This paper provides a method to explain the Prognostics and Health Management (PHM) in terms of fundamental concepts of science within the irreversible thermodynamic framework. The common definition of damage, which is widely used to measure the...
The objects in Nature cannot be simply described in terms of the Euclidean geometry. It is difficult to find natural objects that can be represented as perfect spheres, planes and stright lines. Unfortunatelly, when researchers are intent on describing Nature in detail, they usually fall in mathematical descriptions that are extremately complex, many times with no solution. The fractal geometry...
A simple thermodynamic model of the main transition in pure lipid bilayers is presented. The basic relations for cooperativity, aggregation degree and fractional number of molecules are derived. The experimental heat capacity measurements of uni- and multilamellar phospholipid vesicles are analysed within the context of this model, and the transition characteristics are obtained. It is demonstr...
This paper applies a statistical thermodynamic approach to the kinetics of microbial growth influenced by pH. A general equation is developed and shown to provide a good theoretical basis for the existing pH models that have been widely used to describe the effects of pH on microbial growth kinetics. Four experimental data sets are used to test the general equation developed. The four data sets...
A scheme is presented which allows for the computation of the topological pressure and power spectra associated with equilibrium measures from a given time series. Its convergence properties are demonstrated on numerical data sets obtained from the Lozi and the Henon map. Numerical evidence for sharp peaks in the power spectrum of the non{hyperbolic phase is given and supported by estimates usi...
A new ohmic contact scheme for gallium nitride is presented. The use of Nitrideforming metal Over Gallide-forming metal, “NOG”, can modify the thermodynamic activity of N and Ga near the interface. This in turn can modify the near-surface point defect concentrations, particularly the vacancies of Ga and N. The principle of this contact scheme was shown to be consistent with results from Ni/Au, ...
We study the dynamic and thermodynamic origin of non-canonical equilibria, and we discuss their connection with the generalized central limit theorem and the micro-canonical Boltzmann principle. We reach the conclusion that the zeroth law of thermodynamics and the Boltzmann principle are fulfilled thanks to an apparent fault turned into a benefit: the dynamic approach can only produce a truncat...
We introduce a simple and predictive model for determining the phase stability of ternary phospholipid-cholesterol mixtures. Assuming that competition between the liquid and gel order of the phospholipids is the main driving force behind lipid segregation, we derive a Gibbs free energy of mixing, based on the thermodynamic properties of the lipids main transition. A numerical approach was devis...
In this work, two different approaches – an iterative thermodynamic method and a neural network model – are proposed and compared for the modeling of steam turbines. The iterative thermodynamic model can predict steam mass flow, pressure, temperature, enthalpy and power on each turbine drum. The NN model can predict the generated mechanical power. Both models have been trained and validated on ...
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