Pollution occurs when the concentration of various chemical or biological constituents exceed a level implying negative impact on amenities, the eco-system, resources and human health. Oil spills are the serious environmental   hazards which often exhibit long-term impacts. The main objective of response to an oil spill is to reduce its impact on nature and human health. This paper allows us to...

In the present investigation, the magnetohydrodynamic Falkner-Skan flow of tangent hyperbolic nanofluids over a stretching/shrinking wedge with variable suction, internal heat generation/absorption and chemical reaction with activation energy have been scrutinized. Nanofluid model is composed of “Brownian motion’’ and “Thermophoresis’’. Transformed non-dimensional coupled non-linear equations a...

Cumene hydroperoxide (CHP) is widely used in chemical processes, mainly as an initiator for the polymerization of acrylonitrile-butadiene-styrene. It is a typical organic peroxide and an explosive substance. It is susceptible to thermal decomposition and is readily affected by contamination; moreover, it has high thermal sensitivity. The reactor tank, transit storage vessel, and pipeline used f...

The Direct Simulation Monte Carlo (DSMC) method is used to simulate the flow of rarefied gases. In the Macroscopic Chemistry Method (MCM) for DSMC, chemical reaction rates calculated from local macroscopic flow properties are enforced in each cell. Unlike the standard total collision energy (TCE) chemistry model for DSMC, the new method is not restricted to an Arrhenius form of the reaction rat...

Proteins fold and function inside cells that are crowded with macromolecules. Here, we address the role of the resulting excluded volume effects by in vitro spectroscopic studies of Pseudomonas aeruginosa apoazurin stability (thermal and chemical perturbations) and folding kinetics (chemical perturbation) as a function of increasing levels of crowding agents dextran (sizes 20, 40, and 70 kDa) a...

The Synthesis and Systematic Evaluation of Modified Polymeric Foams and Electrically Conductive Polyimide/Carbon/Metal Films by John Macharia Kinyanjui Dr. David W. Hatchett, Examination Chair Assistant Professor of Chemistry University of Nevada, Las Vegas Thermally processed PU foams are examined as a function of processing temperatures (25, 45, 65, and 85°C) at the side, middle, and center o...

Power generation limits are evaluated via optimization for various energy converters, such like thermal, solar, chemical, and electrochemical engines, in particular fuel cells. Thermodynamic analyses lead to converters’ efficiencies, which help to solve problems of optimal upgrading and downgrading of resources. While methods of static optimization, i.e. differential calculus and Lagrange multi...

Density fingering of exothermic autocatalytic fronts in vertically oriented porous media and Hele-Shaw cells is studied theoretically for chemical reactions where the solutal and thermal contribution to density changes have opposite signs. The competition between these two effects leads to thermal plumes for ascending fronts. The descending fronts behave strikingly differently as they can featu...