The aromatic compounds of Artemisia annua were extracted by supercritical carbon dioxide. Supercritical carbon dioxide extraction of volatile flavor compounds from Artemisia annua was performed at pressure 150bar and temperature 40oC. The flow rate of CO2 was 20 g/min and the flow rate of ethanol as an entrainer was 5% of CO2 used. The extraction time was 1 h. The trapped sample by cold trap 1 ...

The objective of this work has been the co-precipitation of the coating material Ethyl Cellulose (EC) and two natural extracts (IDOKI SCF Technologies), R1 and P1, using the Supercritical Antisolvent (SAS) precipitation technique with supercritical carbon dioxide (SC-CO2), in order to obtain active microparticles. EC is a hydrophobic material widely used for controlled delivery systems, sustain...

The gasification of an aqueous suspension of lignite from Alexandria coalfield (Ukraine) under the supercritical pressure was studied. The initial rates of the formation of hydrogen, carbon dioxide and methane were evaluated. The mutually stimulating interaction of the components of "brown coal-water-mineral matter" system was shown due to the influence of nanoscaled water medium on the formati...

This Account reports the synthesis and characterization of dendrimer-encapsulated metal nanoparticles and their applications to catalysis. These materials are prepared by sequestering metal ions within dendrimers followed by chemical reduction to yield the corresponding zerovalent metal nanoparticle. The size of such particles depends on the number of metal ions initially loaded into the dendri...

Injection of carbon dioxide in deep saline aquifers is considered as a method of carbon sequestration. The efficiency of this process is dependent on the fluid-fluid and rock-fluid interactions inside the porous media. For instance, the final storage capacity and total amount of capillary-trapped CO2 inside an aquifer are affected by the interfacial tension between the fluids and the contact an...

Supercritical carbon dioxide (SC-CO2 ) has been used for the first time as a reaction medium for the dehydration of glycerol to acrolein catalyzed by a solid acid. Unprecedented catalyst stability over 528 hours of time-on-stream was achieved and the rate of coke deposition on the zeolite catalyst was the lowest among extensive previous studies, showing potential for industrial application. Cok...

Dioxide and Extraction Efficiency of Astaxanthin Extraction from H. pluvialis Duangkamol Ruen-ngam, Artiwan Shotipruk, Motonobu Goto, and Prasert Pavasant∗ Department of Chemical Engineering, Faculty of Engineering, Chulalongkorn University, Thailand Bioelectrics Research Center, Kumamoto University, Japan Corresponding author, email: [email protected] (P. Pavasant) and [email protected] ...

Using a continuous flow apparatus, the solubility of tridodecylamine (TDA) in supercritical CO2 (scCO2), have been measured at temperatures of 308, 318, and 328 K in the pressure range of (8-40) MPa and a flow rate of 150 ± 10 mL min. At 308 and 318 K the solubility increases with pressure up to 15 MPa where it reaches a plateau. At 328 K the solubility increases with pressure up to 35 MPa and ...

The state of aggregation of water dissolved in supercritical carbon dioxide has been investigated under isobaric heating (T=40-340°C, P=250 bar) using infrared absorption and Raman scattering spectroscopies. Quantitative analysis of experimental spectra has shown that below 100°C, water exists only in its monomeric form (solitary water surrounded by CO2 molecules) whereas H-bonded species, name...

In this study, we demonstrate a rapid treatment method for producing a needle-like nanowire structure on a hot-dip galvanized sheet at a temperature of 50 °C. The processing method involved only supercritical carbon dioxide and water to induce a reaction on the zinc surface, which resulted in growth of zinc hydroxycarbonate nanowires into flower-like shapes. This artificial patina nanostructure...