We present a theory for Raman scattering by current-carrying molecular junctions. The approach combines a nonequilibrium Green's function (NEGF) description of the nonequilibrium junction with a generalized scattering theory formulation for evaluating the light scattering signal. This generalizes our previous study [M. Galperin and A. Nitzan, Phys. Rev. Lett. 95, 206802 (2005); J. Chem. Phys. 1...

The Raman spectrum and particularly the Raman scattering intensities of monoclinic β-Ga2O3 are investigated by experiment and theory. The low symmetry of β-Ga2O3 results in a complex dependence of the Raman intensity for the individual phonon modes on the scattering geometry which is additionally affected by birefringence. We measured the Raman spectra in dependence on the polarization directio...

Research activity: Materials science of magnetic and ferroelectric oxides, semiconductor nanostructures, optoelectronic device design, and characterization of monolithically-integrated GaNand InP-based optoelectronic devices. Primary research interest is in the field of far-IR Ellipsometry, Transmission, and Raman Spectroscopy, Nanoscale High-Angular Resolution X-ray Diffraction, X-ray Standing...

Plasmonic nanostructures for unifying surface enhanced Raman and Infrared Absorption spectroscopy

A novel effect of population transfer in a five-level system is analyzed. This population transfer effect is found to be a version of a Raman process, which is facilitated and assisted by coherence effects, acting to close other available decay channels.

für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...

In this paper we report the measurement of the direct fifth-order electronically nonresonant intermolecular response from liquid CS2 at room temperature. We recently demonstrated that all previous attempts to measure the direct fifth-order response were dominated by third-order cascaded signals @J. Chem Phys. 111, 3105 ~1999!#. Here we show that phase matching considerations can be used to prov...