Alico, Robert K. (St. Bonaventure University, St. Bonaventure, N.Y.), and Francis W. Liegey. Growth of Desulfovibrio desulfuricans, under heterotrophic and anaerobic conditions. J. Bacteriol. 91:1112-1114. 1966.-Growth of Desulfovibrio desulfuricans was investigated under heterotrophic and anaerobic conditions. For initial growth to occur, it was found that the E(h) or redox potential must be a...

The growth of C. fetus fetus, C. fetus venerealis and C. fetus venerealis biotype intermedius was examined in 10 liquid media. From the data obtained, a 10% inoculum size and an oxygen level of 6% seemed imperative for consistent growth, especially for the C. fetus venerealis strain. A lowered redox potential obtained by the addition of 0, 1% cysteine-HC1 to the media was stimulatory. The mediu...

Bicyclic nitroxyl derivatives, such as 2-azaadamantane N-oxyl (AZADO) and 9-azabicyclo[3.3.1]nonane N-oxyl (ABNO), have emerged as highly effective alternatives to TEMPO-based catalysts for selective oxidation reactions (TEMPO = 2,2,6,6-tetramethyl-1-piperidine N-oxyl). Their efficacy is widely attributed to their smaller steric profile; however, electrocatalysis studies described herein show t...

Chemiluminescence (CL) that appears during oxidation of lecithin and ascorbate has been studied. A simple system consisting only of purified lecithin, which has one double bond, and ascorbate as a physiological reductant with a low redox potential, was used. The CL spectrum of lecithin contain a strong band lying in the near infrared, and three bands at 20 900 cm-1, 17 700 cm-1 and 15 800 cm-1,...

Two diacetylide-triphenylamine hole-transport materials (HTM) with varying redox potential have been applied in planar junction TiO2-[CH3NH3]PbI3-xClx solar cells leading to high power-conversion efficiencies up to 8.8%. More positive oxidation potential of the HTM gives higher VOC and lower JSC illustrating the role of matching energy levels, however both HTMs gave efficient cells despite a di...

Rapid advances in mass spectrometry have allowed for estimates of absolute concentrations across entire proteomes, permitting the interrogation of many important biological questions. Here, we focus on a quantitative aspect of human cancer cell metabolism that has been limited by a paucity of available data on the abundance of metabolic enzymes. We integrate data from recent measurements of abs...

Reduction-oxidation or redox potential is typically collected by measuring redox at a single time interval and returning to the electrode to collect subsequent intervals to generate a temporal gradient of changes in redox. Typically, intervals between sampling are on the scale of hours, days, and weeks, rather than one, five, or 20 minutes due to logistical constraints of collection. These cons...

Mathematical modelling of the oxidation reduction redox potential (ORP) of an electrolyte has been carried out for a batch system comprising an electrochemical reactor and an electrolyte circuit containing a redox couple. The ORP can be useful to monitor the environmental impact of chemical species in solution that represent a risk to the environment. Considerations of four fundamental equation...

Five electroactive ferrocene tags for labelling of biomolecules are contrasted with regard to conjugation reactivity with amine and thiol moieties, stability to loss of electrochemical activity, and impact of molecular structure on the redox potential of the free and DNA-conjugated forms.

Here, we provide the NMR spectra and AFM data for antioxidant micelles prepared from amphiphilic PAM-PDA block copolymers composed of a poly(N-acryloyl morpholine) and a redox-active catechol-bearing block with different catechol content. We also provide details of the electrochemical analysis that showed micelles higher catechol content had a similar redox potential with the small catechol com...