Thermal properties of compost bulking materials affect temperature and biodegradation during the composting process. Well determined thermal properties of compost feedstocks will therefore contribute to practical thermodynamic approaches. Thermal conductivity, thermal diffusivity, and volumetric heat capacity of 12 compost bulking materials were determined in this study. Thermal properties were...

In calorimetry and particularly in heat capacity measurements, different characteristic relaxation time constants may perturb the experiment which cannot be considered at thermodynamic equilibrium. In this case, thermodynamics of irreversible processes has to be taken into account and the calorimetric measurements must be considered as dynamic. In a temperature modulated experiment, such as ac-...

Cp = heat capacity at constant pressure, J= K kg Cv = heat capacity at constant volume, J= K kg c = concentration, mol=m E = total energy, J=m H = shape factor, = , dimensionless h = specific enthalpy, J=kg h = heat of formation, J=kg J = diffusive mass flux, kg=m s Keq = equilibrium constant k = reaction rate coefficient Le = Lewis number, dimensionless M = Mach number, dimensionless ns = tota...

At temperatures between 7.5 °C and 20 °C as well as 26 °C and 40 °C we have recorded the densities and specific heat at constant pressure for critical mixtures of polystyrene in cyclohexane. The degrees of polymerization were N=288 (critical temperature T(c)=9.77 °C ) and N=6242 (T(c)=27.56 °C), respectively. In the two-phase regime a series of reproducible events exists in the specific-heat tr...