A new thiosemicarbazone based-sorbent matrix with sensitive selectivity and accurate spectrophotometric method was proposed for the determination of vanadium (IV) using thiophene-2carboxaldehyde thiosemicarbazone. In our earlier paper we have reported the synthesis, complexetion and analytical data of the sorbent material. It is also characterized by FAB-Mass, IR-spectra, UV-Vis spectroscopy an...

Air-blown gasification of biomass in fluidized bed reactors produces relatively low concentrations of hydrogen. The combination of a catalyst and calcium-based sorbent is being developed to increase the efficiency of converting producer gas from biomass gasification into hydrogen. The conversion process entails reforming the methane and tar, and converting carbon monoxide into hydrogen by the w...

An analytical procedure for straight-forward quantification of rare earth elements (REEs) in tea was developed. The method consists of three steps: first, dry tea powder is converted into an aqueous sample solution using a microwave-assisted digestion procedure. Then, the REEs are retained on newly designed sorbent particles and are thus effectively extracted from the sample digest. Then, the R...

This paper presents results that illustrate the recycling of a bamboo derived sorbent used for the capture of elemental mercury (Hg). The bamboo derived sorbent used is essentially a HCl functionalized activated carbon prepared from carbonization and CO2 activation of raw bamboo, that could potentially provide an alternative way to existing methods in removing mercury from flue gases from coal-...

Ordered nanoporous silica (MSU-H) with high surface area has been utilized as a solid substrate of a surface-modified hybrid sorbent for the application to the removal of U(VI). Carboxymethylated polyethyleneimine (CMPEI) with a strong complexing property has been introduced to the pore surface of MSU-H substrate. CMPEI-modified MSU-H (CMPEI/MSU-H) has been characterized by scanning electron mi...

A method of microextraction by packed sorbent (MEPS) followed by liquid chromatography with diode array detection has been developed and optimized for the extraction of six tricyclic antidepressants (amitriptyline, nortriptyline, imipramine, desipramine, doxepin, nordoxepin) from human serum. The optimal parameters of MEPS extraction (type of sorbent, volume of sample, composition, and volume o...

BACKGROUND Based on the noticeable toxicity and numerous application of mercury in industries, removal of mercury vapor through sorbent is an important environmental challenge. PURPOSE OF THE STUDY Due to their highly porous and hollow structure, large specific surface area, light mass density and strong interaction, Single-Walled Carbon Nanotubes (SWCNTs) sorbent were selected for this inves...

this study describes the synthesis of molecularly imprinted polymers (mips) by using an anti-che ops, namely dursban, as a template. non-covalent bulk polymerization was successfully applied to synthesis different imprinted and non-imprinted polymers with maa, mma, aa, and 4-vpy as monomer in selected porogens (chloroform, toluene, and acetonitrile). in order to evaluate the template binding of...

Aquatic sediments contaminated with heavy metals originating from mining and metallurgical activities pose significant risk to the environment and human health. These sediments not only act as a sink for heavy metals, but can also constitute a secondary source of heavy metal contamination. A variety of sorbent materials has demonstrated the potential to immobilize heavy metals. However, the com...

The determination of extremely small quantities of DNA from complex biological sample matrices represents a significant bottleneck in nucleic acid analysis. In this study, polymeric ionic liquid (PIL)-based solid-phase microextraction (SPME) was applied for the extraction and purification of DNA from crude bacterial cell lysate with subsequent quantification by real-time PCR (qPCR) analysis. Us...