Laminar, sooting, ethylene-fuelled, co-flow diffusion flames at atmospheric pressure have been studied experimentally and theoretically as a function of fuel dilution by inert nitrogen. The flames have been investigated experimentally using a combination of laser diagnostics and thermocouple-gas sampling probe measurements. Numerical simulations have been based on a fully coupled solution of th...

The mutagenic activity of the polycyclic aromatic hydrocar bon-containing fraction of several soot samples was measured in Salmonella typhimurium, using resistance to the purine analog 8-azaguanine as a genetic marker. A postmitochondrial supernatant derived from livers of phénobarbitaland/or Aroclor-pretreated male Sprague-Dawley rats was incorporated into all assays to allow metabolism of pr...

The multiscale full-spectrum k-distribution (MSFSK) method has become a promising method for radiative heat transfer in inhomogeneous media. The scope of the MSFSK method has been limited to radiation calculations involving inhomogeneous gas mixtures only. The objective of this paper is to develop a MSFSK model that is accurate for inhomogeneous mixtures of both gases and nongray particles, suc...

Diesel and wood combustion are major sources of carbonaceous particles in the atmosphere. It is very hard to distinguish between the two sources by looking at soot particle morphology, but clear differences in the chemical structure of single particles are revealed by C(1s) NEXAFS (near edge X-ray absorption fine structure) microspectroscopy. Soot from diesel combustion has a dominant spectral ...

This paper describes the modifications and evolution of a thermal pulse combustionmodel for predicting the combustion oscillations of an aerovalved 250 kW pulse combustorincorporating a soot formation-combustion model. Validation of the model is carried out from theexperimental data of an aerovalved Helmholtz type pulse combustor, where a sinusoidal air inlet massflow coupled with pressure osci...

Engineering the interface between different components of heterogeneous catalysts at nanometer level can radically alter their performances. This is particularly true for ceria-based catalysts where the interactions are critical for obtaining materials with enhanced properties. Here we show that mechanical contact achieved by high-energy milling of CeO2-ZrO2 powders and carbon soot results in t...

This study describes the development of kinetic models for platinum-ceria-zirconia (Pt/CexZr1−xO2)-catalysed diesel particle filter (DPF) regeneration. Such models have a practical purpose in that they can be used to calculate source terms in 3D flow models, and they also have an intrinsic interest for the understanding of the mechanisms of catalysed soot oxidation. The core of this kinetic ana...

Article is made available in accordance with the publisher's policy and may be subject to US copyright law. Please refer to the publisher's site for terms of use. The MIT Faculty has made this article openly available. Please share how this access benefits you. Your story matters. [1] We have studied ice formation at temperatures relevant to homogeneous and heterogeneous ice nucleation, as well...

Air deposition is a dominant transport mechanism for many hydrophobic organic pollutants (HOCs) to the Great Lakes. Our previous research has shown that soot exhibits large surface areas with high organic carbon contents suggesting the potential for strong HOC partitioning. As yet, however, clear data showing the link between HOCs such as PAHs to the deposition of soot into the Lakes (a propose...

The development of a combined dual-pump coherent anti-Stokes Raman scattering (CARS) and laser-induced incandescence (LII) instrument for the spatially resolved measurement of subgrid-scale temperature/soot data in liquid-fueled pool fires is discussed. Temperature pdfs obtained from the N2 Qbranch CARS signal at the center of a 2-m-diameter toluene/methanol pool fire are summarized. A more det...