Under solvothermal conditions the unprecedented nonanuclear Fe(III) aggregate [Fe9(mu3-O)4(mu-OH)4(hpdta)4]5- is formed through the formal encapsulation of [Fe(H2O)6]3+ by four [Fe2(hpdta)(H2O)2]+ units: the aggregates have ground state spins of S= 13/2 while the observed hysteresis below 1.8 K results from inter-cluster antiferromagnetic coupling.

Porous copper zinc tin sulfide (CZTS) thin film was prepared via a solvothermal approach. Compared with conventional dye-sensitized solar cells (DSSCs), double junction photoelectrochemical cells using dye-sensitized n-type TiO(2) (DS-TiO(2)) as the photoanode and porous p-type CZTS film as the photocathode shows an increased short circuit current, external quantum efficiency and power conversi...

Metal organic frameworks (MOFs) of copper and zinc synthesized with 1,4benzenedicarboxylic acid and N,N-dimethylformamide at room temperature and by solvothermal method is reported in this paper. The MOFs were characterized by Fourier transform infrared spectroscopy (FTIR), Scanning electron microscopy (SEM), High resolution transmission electron microscopy (HR-TEM), X-ray diffraction (XRD) and...

Covalent organic frameworks have been prepared in sustainable solvents by a solvothermal method, and their porosity crystallinity were predicted using QSPR machine learning approaches.

Lignin is a natural biopolymer present in lignocellulosic biomass. During paper pulp production with the Kraft process, it solubilized and degraded lignin then burned to recover energy. In this paper, solvolysis of was studied water water/alcohol mixtures produce oligomers monomers interest, at mild temperatures (200–275 °C) under inert atmosphere. It found that presence alcohol type (methanol,...

A universal and robust strategy using polyurethane sponge as a precursor was developed to synthesize highly-soluble nitrogen-doped carbon quantum dots via solvothermal method.