The variational asymptotic method for unit cell homogenization is used to find the sensitivity of the effective properties of periodically heterogeneous materials, within a periodic base-cell. The sensitivities are found by the direct differentiation of the variational asymptotic method for unit cell homogenization (VAMUCH) and by the method of adjoint variables. This sensitivity theory is impl...

Predicting and controlling the microstructure evolution within a material are considered as the ‘‘holy grail’’ of materials science and engineering. Many important engineering materials are designed by controlling their phase transformations and microstructure evolution. Examples include the improvement of mechanical properties through solid-state precipitation reactions in Nibased superalloys ...

Recently, the phase-field method has been extended and utilized across many fields of materials science. Since this method can incorporate, systematically, the effect of the coherency induced by lattice mismatch and the applied stress as well as the external electrical and magnetic fields, it has been applied to many material processes including solidification, solid-state phase transformations...

orpiment, getchellite and stibnite from zarshuran deposit, nw iran, exhibit extensive as-sb substitution. there are four known minerals along as2s3-sb2s3 join, i.e. orpiment (as2s3), wakabayashilite [(as,sb)20s30], getchellite (assbs3) and stibnite (sb2s3). extensive mineralogical studies by scanning electron microscope (sem) and electron probe micro-analyzer (epma) indicate that getchellite fr...

Orpiment, getchellite and stibnite from Zarshuran deposit, NW Iran, exhibit extensive As-Sb substitution. There are four known minerals along As2S3-Sb2S3 join, i.e. orpiment (As2S3), Wakabayashilite [(As,Sb)20S30], getchellite (AsSbS3) and stibnite (Sb2S3). Extensive mineralogical studies by scanning electron microscope (SEM) and electron probe micro-analyzer (EPMA) indicate that getchellite fr...

Designing optimal microstructures for solid oxide fuel cell (SOFC) electrodes is complicated due to the multitude of electro-chemo-physical phenomena taking place simultaneously that directly affect working conditions of a SOFC electrode and its performance. In this study, a new design paradigm is presented to obtain a balance between electrochemical sites in the form of triple phase boundary (...

In this paper, the correlation of reflection loss measured by an ultrasonic shear wave reflection method and the microstructure in cement-based material is investigated. Three cement pastes (Portland cement type I) with different water-cement ratios (0.35, 0.50 and 0.60) cured at 25 °C were examined. The ultrasonic shear wave reflection factor (WRF) was measured by the wave reflection technique...