Microcrystalline cellulose (MCC) samples pretreated by ionic liquid (ILs)H2O mixtures were studied for application in a pyrolysis process. A 1-ethyl3-methylimidazolium methanesulfonate [Emim][MeSO3]-H2O mixture with solid acid catalyst NafionNR50 was used in the pretreatment process. A lower amount of hydrogen bonding between neighboring pretreated MCC chains resulted from a less ordered cellul...

In a previous study, selective degradation of carbohydrates versus lignin in buried woods was demonstrated by non-destructive spectroscopy (C NMR) and destructive wet chemical methods (acid hydrolysis and alkaline CuO oxidation). In this paper, spruce, alder and oak woods deposited in coastal sediments and their recent equivalents are characterized by pyrolysis-mass spectrometry and pyrolysis-g...

fast pyrolysis is an attractive technology for biomass conversion, from which bio-oil is the preferred product with a great potential for use in industry and transport. corn wastes (cob and stover) and eucalyptus wood are widely being produced throughout the world. in this study, fast pyrolysis of these two materials were examined under the temperature of 500 °c; career gas flow rate of 660 l h...

Qualitative identification of sorbed volatile organic compounds (VOCs) on biochar was conducted by headspace thermal desorption coupled to capillary gas chromatographic-mass spectrometry. VOCs may have a mechanistic role influencing plant and microbial responses to biochar amendments, since VOCs can directly inhibit/stimulate microbial and plant processes. Over 70 biochars encompassing a variet...

Different species and genotypes of Miscanthus were analysed to determine the influence of genotypic variation and harvest time on cell wall composition and the products which may be refined via pyrolysis. Wet chemical, thermo-gravimetric (TGA) and pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS) methods were used to identify the main pyrolysis products and determine the extent to which...

Sensitivity of piezoelectric-diaphragm type ultrasonic microsensors were investigated with sol-gel derived lead-zirconate-titanate (PZT) films prepared through various pyrolysis temperatures. The residual stress of the PZT film should be precisely controlled because the sensor diaphragms show static deflection by buckling and highly sensitive sensors have been realized on upward-buckled diaphra...

Coconut is a high-quality agricultural product of the Asia-Pacific region. In this paper, coconut shell which mainly composed of cellulose, hemicellulose, lignin was used as a raw material for coconut shell oil from coconut shell pyrolysis. The influence of the pyrolysis temperature, heating rate and particle size on coconut oil yield was investigated, and the effect of heating rate on coconut ...

Seeking a clean alternative energy resource is inevitable because of the limited fossil fuel energy resources and greenhouse gas emissions issue. Recently, advances in chemical and fuel processing technologies allow us to convert biomass to energy products with high energy density and value. Fast pyrolysis process is among the promising technologies for converting biomass to bio-oil and combust...

Transient changes in wettability complicate the prediction of biochar's hydrologic effects. Biochar wetting properties were characterized from poultry litter biochar (PLBC) produced from slow pyrolysis at temperatures between 300 and 600°C with water drop penetration time (persistence of hydrophobicity) and contact angle (CA; severity of hydrophobicity) measurements. Hydrophobicity was associat...

Modeling is regarded as a suitable tool to improve biomass pyrolysis in terms of efficiency, product yield, and controllability. However, it crucial develop advanced models estimate products' yield composition functions type/characteristics process conditions. Despite many developed models, most them suffer from insufficient validation due the complexity determining chemical compounds their qua...