new hetero-binuclear hg-cu schiff base complexes were prepared by reaction of 2,2'-[1,1'-(2,2-‎dimethylpropane-1,3-diyldinitrilo)-diethyldyne]diphenolato}copper(ii) (cul1) and 6,6'-x-2,2'-[(2,2-‎dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato copper(ii) [(x = ethoxy (cul2) and ‎methoxy (cul3)], with hgcl2 to give [cu(l1)hgcl2] (1), [cu(l2)hgcl2] (2), and [cu...

new hetero-binuclear hg-cu schiff base complexes were prepared by reaction of 2,2'-[1,1'-(2,2-‎dimethylpropane-1,3-diyldinitrilo)-diethyldyne]diphenolato}copper(ii) (cul1) and 6,6'-x-2,2'-[(2,2-‎dimethylpropane-1,3-diyl)bis(nitrilomethanylylidene)]diphenolato copper(ii) [(x = ethoxy (cul2) and ‎methoxy (cul3)], with hgcl2 to give [cu(l1)hgcl2] (1), [cu(l2)hgcl2] (2), and [cu(l3)hgcl2] (3), ‎res...

An efficient one-pot three-component procedure for the synthesis of new chiral spiro-oxindolopyrrolizidines with highly regio-, diastereo-, and enantioselective from 1,3-dipolar cycloaddition of azomethine ylides and optically pure active cinamoyl oxazolidinone are described. The process occurs at room temperature in aqueous ethanol as green solvent and in the absence of any bidentate chelating...

A two-dimensional nanolayered polyoxomolybdate, [4,4´-H2bipy] [Mo7O22].H2O (1), where 4,4´-bipy = 4,4´-bipyridine, was prepared and characterized by FT-IR and atomic absorption spectroscopies, transmission electron microscopy (TEM), X-ray single crystal and powder diffraction (XRD), and thermogravimetric analysis. The catalytic performance of 1 was assessed in the epoxidation of some olefins em...

Porous clay heterostructures (PCH) based on modified montmorillonite were synthesized using different reaction conditions (different hydration degrees, pH values and reaction times). The PCH precursors and PCH were characterized using FTIR Spectroscopy and X-Ray Diffractions (XRD). The XRD results showed that basal distance of porous clay heterostructures was significantly influenced by the mod...

An efficient one-pot three-component procedure for the synthesis of new chiral spiro-oxindolopyrrolizidines with highly regio-, diastereo-, and enantioselective from 1,3-dipolar cycloaddition of azomethine ylides and optically pure active cinamoyl oxazolidinone are described. The process occurs at room temperature in aqueous ethanol as green solvent and in the absence of any bidentate chelating...