abstract: â in this study, the change in the crystalline structure of gas hydrate was predicted for ternary mixture of methane-ethane-water. for this purpose, the tangent plane distance (tpd) minimization method was used. first, the calculations were performed for the binary mixtures of methane-water and ethane-water as the gas and liquid phases. the results show that for a binary mixture of th...

in this work, experimental kinetics data of methane hydrate decomposition at temperatures ranging from 272.15 to 276.15 k and at pressures ranging from 10 to 30 bars were modeled by using chemical affinity. this model proposed a macroscopic model which is independent of any intermediate mechanism like heat or mass transfer. the results show there is good agreement with experimental data. also t...

A 403-day in situ field experiment at Ocean Drilling Program Site 892B sought to quantify the flux of methane along a fluid-active fault and to experimentally determine rates of methane hydrate and authigenic carbonate deposition associated with fluid expulsion from the borehole. An instrument package was deployed that osmotically sampled fluid, measured borehole pressure and flow rates, and co...

Replacement of methane with carbon dioxide in hydrate has been proposed as a strategy for geologic sequestration of carbon dioxide (CO(2)) and/or production of methane (CH(4)) from natural hydrate deposits. This replacement strategy requires a better understanding of the thermodynamic characteristics of binary mixtures of CH(4) and CO(2) hydrate (CH(4)-CO(2) mixed hydrates), as well as thermoph...

The Krishna Godavari (KG) basin is rich in gas hydrate and exhibits an area of wide range of gas hydrate stability zone (GHSZ). In this region, we modeled the base of the gas hydrate stability zone (BGHSZ) utilizing in situ temperature measurements acquired during national gas hydrate program (NGHP) Expedition-01. The bottom simulation reflector (BSR) closely approximates the BGHSZ, and due to ...

Gas hydrates presented as form of segregated bodies have been observed on shallow subsurface sediments. However, most gas hydrate physics models describe that hydrates occur in pore space in deep subsurface sediment. A new model considers gas hydrate as segregated bodies to derive elastic properties of hydrates bearing sediments and gas hydrate saturation. The predicted elastic properties based...

The Michelsen stability and multiphase flash calculation by direct minimization of Gibbs free energy of the system at constant temperature and pressure, was used for systems containing gas hydrates. The solid hydrate phase was treated as a solid solution. The fugacities of all components of the hydrate phase were calculated as a function of compositions by the rearranged model of van der Wa...