Carbon nanomaterials are a new form of carbon based materials which have been receiving much attention for their interesting properties over the past three decades. The materials were initially discovered in 1952 [1] but were only scientifically recognized in 1991 when Iijima submitted a report [2]. An interesting feature of these allotropes of carbon has been the different forms in which they ...

We shed light on the specific hydration structure around a zinc ion of nanosolution restricted in a cylindrical micropore of single-wall carbon nanotube (SWNT) by comparison with the structure restricted in a cylindrical mesopore of multi-wall carbon nanotube (MWNT) and that of bulk aqueous solution. The average micropore width of open-pore SWNT was 0.87 nm which is equivalent to the size of a ...

Conducting composite films containing carbon nanotubes (CNTs) were prepared by using the biopolymer kappa-carrageenan (KC) as a dispersant. Rheological studies indicated that 0.5% w/v was the appropriate KC concentration for dispersing CNTs. Our results showed that multiwalled nanotubes (MWNTs) required less sonic energy than single-walled nanotubes (SWNTs) for the dispersion process to be comp...

The nanotribological characterization of carbon nanotubes is fundamental for the exploration of new sliding applications. In this study, a comprehensive investigation of adhesion, friction and wear of a multiwalled nanotube (MWNT) tip, and SWNT (single-walled nanotube) and MWNT arrays has been carried out. A nonlinear response of the MWNT tip is observed when the tip is brought into and out of ...

Optical properties of a series of finite sized hydrogenated carbon nanotubes with the smallest diameter of 4 A are studied systematically. Their absorption spectra are calculated with the localized-density-matrix method. The semiempirical MNDO parametric method 3 (PM3) Hamiltonian is employed. The finite optical gaps are predicted for the infinite long single-walled carbon nanotubes. Strong ani...

Metallic single-walled carbon nanotubes have been proposed to be good one-dimensional conductors. However, the finite curvature of the graphene sheet that forms the nanotubes and the broken symmetry due to the local environment may modify their electronic properties. We used low-temperature atomically resolved scanning tunneling microscopy to investigate zigzag and armchair nanotubes, both thou...

Diameter controlled and vertically aligned single-walled carbon nanotubes were synthesized from pure and mixed ethanol/acetonitrile feedstock. With increasing acetonitrile concentration in the feedstock, nitrogen incorporation into the sp carbon network increased until saturating at approximately one atomic percent. The incorporation of nitrogen correlates with a significant diameter reduction ...

By using alcohol as the carbon source, a new simple catalytic chemical vapor deposition technique to synthesize high-purity single-walled carbon nanotubes at low temperature is demonstrated. Because of the etching effect of decomposed OH radical attacking carbon atoms with a dangling bond, impurities such as amorphous carbon, multi-walled carbon nanotubes, metal particles and carbon nanoparticl...

the doping reaction of truncated boron nitride and carbon nanotubes with aluminium atom wastheoretically investigated. the am1, pm3, and pm6 semiempirical methods have been used toevaluate the thermochemistry of doping reactions of single walled boron nitride nanotubes andcarbon nanotubes. the enthalpy changes, gibbs free energy changes, and entropy changes of studieddoping reactions were evalu...

In contrast to our previous study (Barth & Marx, 2008) dealing with a currently decreasing research field (high-temperature superconductors) we analyzed here a topic which has raised a strongly increasing interest among researchers: research activities around carbon nanotubes (CNTs or NTs). Carbon nanotubes (often named only nanotubes) are graphite sheets rolled up into cylinders with diameters...