A rigorous model for the simulation of the dynamic behaviour of distillation column including pressure relief has been developed. This model allows the analysis of the influence of different disturbances (failures) on the dynamic behaviour of a methanol/water column. Disturbances of the cooling medium supply to the condenser and the reflux stream have been examined. In this paper the results of...

We present new analytical expressions for minimum energy consumption (1 law) and minimum entropy production, or lost work (2 law), in complex distillation arrangements. These simple, but exact, expressions apply to ideal mixtures and an infinite number of stages, and the relative volatility is the only required component property. The simple Vmin-diagram is shown to be very useful in evaluating...

This work has been carried out to demonstrate the performances of four different state space models in the model predictive control system of a reactive distillation process that was used for the production of ethyl acetate. The state space models of the reactive distillation process were developed with the aid of System Identification Toolbox of MATLAB using the data acquired from the reactive...

In this work, applications of exergy and economic concepts to compression, heat exchange, and separation processes were used for calculation of the irreversibility rate, thermodynamic efficiency, and internal rate of return (IRR) of the profitability. A case study based on a real process, the purification of 1,2dichloroethane (DCE) in a high-purity distillation column, is presented. This column...

The multi®essel batch distillation column, as well as con®entional batch distillation, ( ) can be operated in a closed total reflux mode where the products are collected in ®essels along the column. A pre®iously proposed and simulated feedback control strategy for the closed operation is to indirectly adjust the ®essel holdups by using the reflux flow out of the ®essel to control the termperatu...

An important amount of work exists on the topic of optimal operation and control of batch distillation though it is still based on the assumption of an accurate process model being available. While this assumption is valid from a theoretical point of view, there will always remain the challenge of practical applications. Reinforcement Learning (RL) has been recognised already as a particularly ...