Six high-entropy rare earth tetraborides of the tetragonal UB4-prototyped structure have been successfully synthesized for first time. The specimens are prepared from elemental precursors via high-energy ball mill and in-situ reactive spark plasma sintering. sintered >98 % in relative densities without detectable oxide impurities (albeit presence minor hexaborides some compositions). No seconda...

Ingestion of foreign bodies in the pediatric population is common and magnet ingestion is known to cause a significant morbidity. Rare-earth magnets are small 3-6 mm diameter spherical powerful magnets that are sold as popular desk toys for adults and were previously found in construction toys in attractive colors for children to play with. We describe 2 young healthy children who ingested rare...

Type-I clathrates possess extremely low thermal conductivities, a property that makes them promising materials for thermoelectric applications. The incorporation of cerium into one such clathrate has recently been shown to lead to a drastic enhancement of the thermopower, another property determining the thermoelectric efficiency. Here we explore the mechanism of the incorporation of rare earth...

26 Einstein J. Biol. Med. (2008) 24:26-31. A method of analysis is proposed which utilizes the characteristic melting points of the hydrated salts and the liquidus curves of the binary salt mixtures for the estimation of the composition of rare earth mixtures. Several binary salt systems were investigated, employing very pure simple and double rare earth nitrates to provide basic information co...

The dissolution rates of rare earth oxides and two types of rare earth containing functional materials into water, saline solution, and Gamble's fluid were measured in order to evaluate the biological effects of rare earth-containing functional materials. The tested materials were yttrium, lanthanum, cerium and neodymium oxides, and neodymium-boron-iron magnet alloy (NdBFe) and lanthanum-mish-m...

A method is proposed to determine trace rare earth impurities in high-purity CeO2 by HPLC combined with electrothermal vaporization inductively coupled plasma atomic emission spectrometry (ETV-ICP-AES). The chromatographic retention behaviours of the matrix (Ce) and rare earth impurities were studied using 2ethylhexyl hydrogen 2-ethylhexylphosphonate (P507) resin as the stationary phase and dil...