In the title compound, C(14)H(11)BrN(4), the fused benzene and pyrimidine rings are nearly coplanar, making dihedral angles of 1.26 (14) and 3.53 (15)° in the two independent mol-ecules. In the crystal structure, π-π stacking inter-actions [centroid-centroid distances = 3.4736 (19) and 3.5416 (19) Å] and weak N-H⋯N and N-H⋯Br inter-actions contribute to the stability of the structure.
