Within a two-component approach to high T c copper oxides including polaronic couplings, we identify the pseudogap phase as the onset of polaron ordering. This ordering persists in the superconducting phase. A huge isotope effect on the pseudogap onset temperature T * is predicted and in agreement with experimental data. The anomalous temperature dependence of the mean square copper-oxygen ion ...

A method for the simultaneous spectrophotometric determination of cadmium, copper and zinc based on the formation of their complexes with 1,5-bis(di-2-pyridylmethylene)thiocarbonohydrazide is proposed. The absorption curves of these complexes overlap severely in the scanning range 380-480 nm. The analyte concentrations are calculated by a least squares fit of the pure spectra to the mixture spe...

A series of copper(I) amidinates of the general type [(R'NC(R)NR'')Cu](2) (R' and R'' = n-propyl, isopropyl, n-butyl, isobutyl, sec-butyl, tert-butyl; R = methyl, n-butyl) have been synthesized and characterized. These compounds are planar dimers, bridged by nearly linear N-Cu-N bonds. Their properties (volatility, low melting point, high thermal stability, and self-limited surface reactivity) ...

A protein analog of a purple copper center has been constructed from a recombinant blue copper protein (Pseudomonas aeruginosa azurin) by replacing the loop containing the three ligands to the blue copper center with the corresponding loop of the CuA center in cytochrome c oxidase (COX) from Paracoccus denitrificans. The electronic absorption in the UV and visible region (UV-vis) and electron p...

The variation rule of the Volta potential on deformed copper surfaces with dislocation density is determined in this study by using electron back-scattered diffraction (EBSD) conjunction scanning Kelvin probe force microscopy (SKPFM). results show that not linear density. When increases due to deformation pure copper, tends a physical limit. exhibits fractional function relationship only for re...

The anticancer properties of pure copper (II) acetate and copper (II) acetylacetonate, alone and loaded on functionalized sol-gel titania (TiO(2)), were determined in four different cancer cell lines (C6, RG2, B16, and U373), using increasing concentrations of these compounds. The copper complexes were loaded onto the TiO(2) network during its preparation by the solgel process. Once copper-TiO(...

in this study, a feasible green method for the synthesis of copper oxide nanocrystalline is described by using sour cherry juice which has a significant effect on crystalline size, and morphology. the benefits of the green method, not only nanometer scale are formed but also low-cost method are obtained in a normal atmosphere which it has been used (ch3coo)2cu.h2o individually as cu sources. al...

copper thin films with nano-scale structure have numerous applications in modern technology.  in this work, cu thin films with different thicknesses from 50–220 nm have been deposited on glass substrate by dc magnetron sputtering technique at room temperature in pure ar gas. the sputtering time was considered in 4, 8, 12 and 16 min, respectively. the thickness effect on the structural, morpholo...

The world’s rapidly dwindling crude oil supplies, their rising cost and the rapid growing of automobile pollutions from fossil fuels have led to an intensive search for alternative fuels. Experiments were conducted to evaluate the performance and control the exhaust emissions from two-stroke, single cylinder, spark ignition (SI) engine, with alcohol blended gasoline (80% gasoline and 20% ethano...