Introducing a hydrophobic property to vertically aligned hydrophilic metallic nanorods was investigated experimentally and theoretically. First, platinum nanorod arrays were deposited on flat silicon substrates using a sputter Glancing Angle Deposition Technique (GLAD). Then a thin layer of Teflon (nanopatches) was partially deposited on the tips of platinum nanorod at a glancing angle of θ = 8...

Nanocomposites of multi-walled carbon nanotubes and titanium dioxide (MWCNT/TiO2) were synthesized by the sol-gel method. Regarding hydrophobicity of carbon nanotubes (CNTs), benzyl alcohol was used as the linking agent between CNT powder and TiO2 gel which was prepared from the precursor of titanium tetraisopropoxide. The prepared samples were treated under thermal treatments. A part of the sa...

We present an ink platform for a printable polymer-graphene nanocomposite that is intended for the development of modular biosensors. The ink consists of catechol-modified chitosan and reduced graphene oxide decorated with platinum nanoparticles (rGO-Pt). We modified the chitosan with catechol groups, in order to obtain adhesive properties and improve solubility. Dispersions of rGO-Pt in ethyle...

We introduce an innovative and robust method for the preparation of nanocomposite multilayers, which allows accurate control over the placement of functional groups as well as the composition and dimensions of individual layers/internal structure. By employing the photocross-linkable polystyrene (PS-N(3), M(n) = 28.0 kg/mol) with 10 wt % azide groups (-N(3)) for host polymer and/or the PS-N(3)-...

Single wall Carbon Nanotubes (SWCNTs) are hydrophobic and do not disperse in aqueous solvents. Acid functionalization of SWCNTs results in attachment of carboxy and sulfonate groups to carbon atoms and the resulting acid functionalized product (AF-SWCNTs) is negatively charged and disperses easily in water and buffers. In the present study, effect of AF-SWCNTs on blood erythrocytes was examined...

The reinforcing and conductive performance of carbon nanotube polymer-based nanocomposites depends on the established network its configuration. Within this study, we report underlying mechanisms such formation utilizing single-walled nanotubes (SWCNTs) in low- high-density polyethylene matrices. Mechanisms were theoretically evaluated through Doi–Edwards theory experimentally confirmed plasma ...

Reactive, thermal degradation of py2Pt[MoCp(CO)3]2, (Me)(cod)PtMoCp(CO)3, orfPt3ðdppmÞ3ðCOÞ1⁄2MoðCpÞ g[BPh4]/Vulcan carbon powder composites affords Pt–Mo/carbon nanocomposites containing metal nanoparticles of approximate compositions, PtMo2, PtMo, or Pt3Mo, widely dispersed on the carbon support. Total metal loadings range from 29–58 wt%. When tested as an anode electrocatalyst in a PEM fuel ...

Local chemical functionalization of single-walled carbon nanotubes (SWCNTs) has been developed as a means defect doping to enhance the near infrared photoluminescence properties materials. Wavelength-tunable and exciton trapping-induced bright emission appears from locally functionalized SWCNTs (lf-SWCNTs). Molecularly designed lf-SWCNTs based on our approach produce new dynamic switching funct...