نتایج جستجو برای: potential

تعداد نتایج: 1067793  

2016
Yuriy Gorodnichenko Gerard Roland

We construct a model of revolution and transition to democracy under individualistic and collectivist cultures. The main result is that, despite facing potentially larger collective action problems, countries with an individualistic culture are more likely to end up adopting democracy earlier than countries with a collectivist culture. Our empirical analysis suggests a strong and robust associa...

1995
J. J. de Swart R. A. M. M. Klomp

A review is given of the various Nijmegen potentials. Special attention is given to some of the newest developments, such as the extended soft-core model, the high-quality potentials, and the Nijmegen optical potentials for NN.

Journal: :The Journal of chemical physics 2014
Diego R Alcoba Alicia Torre Luis Lain Ofelia B Oña Pablo Capuzzi Mario Van Raemdonck Patrick Bultinck Dimitri Van Neck

We present a configuration interaction method in which the Hamiltonian of an N-electron system is projected on Slater determinants selected according to the seniority-number criterion along with the traditional excitation-based procedure. This proposed method is especially useful to describe systems which exhibit dynamic (weak) correlation at determined geometric arrangements (where the excitat...

1995
Andrew D. Lewis Richard M. Murray

In this paper we present a deenition of \connguration controllability" for mechanical systems whose Lagrangian is kinetic energy with respect to a Riemannian metric minus potential energy. A computable test for this new version of controllability is also derived. This condition involves a new object which we call the symmetric product. Of particular interest is a deenition of \equilibrium contr...

Journal: :Annual review of physical chemistry 1998
L J Butler

To predict the branching between energetically allowed product channels, chemists often rely on statistical transition state theories or exact quantum scattering calculations on a single adiabatic potential energy surface. The potential energy surface gives the energetic barriers to each chemical reaction and allows prediction of the reaction rates. Yet, chemical reactions evolve on a single po...

Journal: :Nature chemistry 2015
Pablo G Jambrina Diego Herráez-Aguilar F Javier Aoiz Mahima Sneha Justinas Jankunas Richard N Zare

Interferences are genuine quantum phenomena that appear whenever two seemingly distinct classical trajectories lead to the same outcome. They are common in elastic scattering but are seldom observable in chemical reactions. Here we report experimental measurements of the state-to-state angular distribution for the H + D2 reaction using the 'photoloc' technique. For products in low rotational an...

Journal: :SIAM Journal of Applied Mathematics 1996
Michael J. Ward

In a multi-dimensional domain, the slow motion behavior of internal layer solutions with spherical interfaces, referred to as bubble solutions, is analyzed for the nonlocal Allen-Cahn equation with mass conservation. This problem represents the simplest model for the phase separation of a binary mixture in the presence of a mass constraint. The bubble is shown to drift exponentially slowly acro...

Journal: :Journal of the American Chemical Society 2017
Peter R Schreiner

This Perspective describes the emergence of tunneling control as a new reactivity paradigm in chemistry. The term denotes a tunneling reaction that passes through a high but narrow potential energy barrier, leading to formation of a product that would be disfavored if the reaction proceeded by passage over kinetic barriers rather than through them. This reactivity paradigm should be considered ...

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