We consider a discrete polynuclear growth (PNG) process and prove a functional limit theorem for its convergence to the Airy process. This generalizes previous results by Prähofer and Spohn. The result enables us to express the F1 GOE Tracy-Widom distribution in terms of the Airy process. We also show some results, and give a conjecture, about the transversal fluctuations in a point to line las...

We study statistical properties of a continuum model of polynuclear surface growth on an infinite substrate. We develop a self-consistent mean-field theory which is solved to deduce the growth velocity and the extremal behaviour of the coverage. Numerical simulations show that this theory gives an improved approximation for the coverage compared to the previous linear recursion relations approa...

We study a variant of poly-nuclear growth where the level boundaries perform continuous-time, discrete-space random walks, and study how its asymptotic behavior is affected by the presence of a columnar defect on the line. We prove that there is a non-trivial phase transition in the strength of the perturbation, above which the law of large numbers for the height function is modified.

Two new polynuclear heterometallic cluster complexes with [Mn(III)(3)M(II)Na] (M = Mn, Ca) core were synthesized using two in situ formed Schiff bases. The compounds were structurally characterized by single crystal X-ray analysis. The compound with [Mn(III)Ca(II)Na] appeared to catalyse water oxidation which was followed by using Clark electrode and online mass spectrometry.

Three isomeric water-soluble and light-stable silver(I) coordination polymers with a fluorinated carboxylate ligand were prepared by template-controlled method, which show different 2D polymeric coordination structures with a novel layered inorganic connectivity in the solid state. In water solution, they dissociate into several stable polynuclear silver(I) oligomers and exhibit extraordinary a...

This article summarizes the methodological progress that has been made in the vibrational spectroscopy of isolated polynuclear metal oxide clusters, with particular emphasis on free electron laser-based infrared action spectroscopy of gas phase clusters, over the last decade. The possibilities, limitations and prospects of the various experimental approaches are discussed using representative e...

The foregoing experimental cases point to a distinct participation of the udder in the production of agglutinins when the gland is invaded by living or flooded by dead bacteria. The quarter injected reacts at first with a heavy influx of polynuclear leucocytes and later with an increase of agglutinins.

Polynuclear manganese complexes are used as precursors for the synthesis of manganese oxide nanoparticles (MnO NPs). Altering the thermal decomposition conditions can shift the nanoparticle product from spherical, thermodynamically-driven NPs to unusual, kinetically-controlled octapod structures. The resulting increased surface area profoundly alters the NP's surface-dependent magnetism and may...

A pentamethylcyclopentadienyl-iridium complex containing a tricyclic, dianionic, tridentate, scorpionate (facial binding), mixed organic-inorganic ligand was synthesized and characterized by single-crystal X-ray crystallography, as well as polynuclear NMR, UV-vis, and IR spectroscopies. The central cycle of the tridentate ligand consists of a modified boroxine in which two of the boron centers ...

Magnetic anisotropy, in the absence of an external magnetic field, relates to degeneracy lift energy levels. In standard case transition metal complexes, this property is usually modeled by anisotropic spin Hamiltonian and one speaks “zero-field splitting” (ZFS) states. While mononuclear complexes has been extensively described means ab initio quantum mechanical calculations, literature on poly...