The synthesis, characterization, and metal-binding studies of chelate-functionalized dendrimers is reported. Salicylate, catecholate, and hydroxypyridinonate bidentate chelators have been coupled to the surface of both poly(propyleneimine) (Astramol) and poly(amidoamine) (Starburst, PAMAM) dendrimers up to the fifth generation (64 endgroups). A general method has been developed for the facile a...

Introduction: The twin Mars Exploration Rovers (MER) Spirit and Opportunity have explored the Martian surface at Gusev Crater (GC) and Meridiani Planum (MP) for more that 1840 sols (more than 5 Earth years). Their science payload [1] includes instruments for mineralogical (Mössbauer (MB), Mini-TES, and Pancam) and chemical (APXS) analysis and a tool (RAT) for brushing and grinding rock surfaces...

Poly(3-hexylthiophene) (P3HT) matrix has been chemically doped (redox doping) by ferric chloride (FeCl3) with different molar concentrations to get P3HT–FeCl3 charge-transfer complexes. The effect of redox doping on photo-physical, structural, and morphological properties and dc electrical conductivity of P3HT matrices has been examined. The dc conductivity has been measured on films of pristin...

The influence of surfactant hydrocarbon tail on the solute/pseudostationary phase interactions was examined. Four anionic sulfated surfactants with 8-, 9-, 10-, and 11-carbon chains having a polymerizable double bond at the end of the hydrocarbon chain were synthesized and characterized before and after polymerization. The critical micelle concentration (CMC), polarity, and aggregation number o...

In spite of the environmental and commercial interests in the bacterial leaching of pyrite, two central questions have not been answered after more than 35 years of research: does Thiobacillus ferrooxidans enhance the rate of leaching above that achieved by ferric sulfate solutions under the same conditions, and if so, how do the bacteria affect such an enhancement? Experimental conditions of p...

In this research, the quality of wastewater discharged into environment has been investigated. The effluent from solar desalination pond contains large amounts TDS (3.68 grams per liter) and TH (6.50 liter). Since use filter is not economical in case, three types commercial coagulants such as aluminum sulfate, ferric chloride sulfide have used study. main parameters effectiveness inorganic coag...

A simplified scheme of analysis is presented for the determination of free and esterified cholesterol, the phospholipids, and the neutral fats (triglycerides) of blood serum. The hydroxamic acid reaction is used to determine total esterified fatty acids. The phospholipids are determined after acid digestion of a trichloroacetic acid precipitate of protein-phospholipid, and both total and free c...