Results are presented from an ongoing project to study the status and behavior of I and I in the environment. I and I abundances were investigated in precipitation, surface and ground waters from Lower Saxony, Germany, and in soil samples from various European locations. From the analysis of I in rain, I annual deposition densities were determined for the time period from 19971999. We conclude ...

A reliable method for the determination of iodine and molybdenum in milk samples, using alkaline digestion with tetramethylammonium hydroxide and hydrogen peroxide, followed by quadrupole ICP-MS analysis, has been developed and tested using certified reference materials. The use of He+O2 (1.0 ml min(-1) and 0.6 ml min(-1)) in the collision-reaction cell of the mass spectrometer to remove (129)X...

Abstract This study investigates the potential of hydroalcoholic extracts Cistus ladanifer L., Erica Andevalensis and Rubus idaeus L. as a green method for recovery platinum group metals (PGMs) from both synthetic unimetallic solutions multimetallic obtained leaching two different spent automotive catalytic converters (SACC). Experiments with revealed that E. andevalensis R. could separate abou...

Using PM-2 DNA and cytotoxicity assay systems, we have studied several second-generation platinum analogs and compared these to the parent compound cis-diamminedichloroplatinum(II). These results indicate that all planar platinum(II) congeners induced similar effects upon interaction with PM-2 DNA, i.e., alteration of the tertiary DNA conformations. The reactivity of the analogs with DNA depend...

The adsorption of Mn(II) and Co(II) ions from aqueous solution was investigated using batch adsorption experiment at room temperature. The effect of pH, contact time, metal ion concentration and temperature were evaluated. The residual concentrations of the metal ions were determined by atomic absorption spectrophotometer. The results showed that maximum removal of Mn(II) and Co(II) ions occurr...

In the present study, a new magnetic powder based on magnetite can be used as a petroleum crude oil collector. Amidoximes based on rosin as a natural product can be prepared from a reaction between hydroxylamine and rosin/acrylonitrile adducts. The produced rosin amidoximes were used as capping agents for magnetite nanoparticles to prepare hydrophobic coated magnetic powders. A new class of mon...

Most of the mercury contamination in lakes and streams of nonindustrialized regions of the United States and Canada is derived from atmospheric deposition. In order to determine the regional patterns of these inputs, seven mercury-in-precipitation monitoring sites were established in Minnesota, North Dakota, and Michigan. A 3-year study showed that the magnitude of mercury deposition was domina...

Various electrochemical approaches, including potentiodynamic polarization, open circuit potential evolution and electrochemical impedance spectroscopy (EIS), are employed to investigate the degradation behavior of biomedical magnesium alloy under the influence of aggressive ions, such as chloride, phosphate, carbonate and sulfate, in a physiological environment. The synergetic effects and mutu...

This paper presents the results of a study of variation in the chemical composition of wet precipitation over a 16-year period. The ions SO4 2, NO3 , Cl , Ca 2+ , Mg 2+ K + , Na + , NH4 + and H + were analyzed. The correlation analysis showed a high positive correlation among these ions, indicating that anthropogenic emissions were the most important source. Trends in annual concentrations of S...

Studying the earliest stages of precipitation at the nanoscale is technically challenging but quite valuable as such phenomena reflect important processes such as crystallization and biomineralization. Using a quartz nanopipette as a nanoreactor, we induced precipitation of an insoluble salt to generate oscillating current blockades. The reversible process can be used to measure both kinetics o...