Tungsten trioxide nanoparticles with monoclinic structure and average particle size about 80 nm were prepared by the spray pyrolysis method. WO3 nanorods with hexagonal structure and average dimension about 15 × 100 nm were synthesized in gram quantities by modified hydrothermal method at lower temperature and shorter reaction time in comparison to the previous research. Photo de...

Organic pollution is the term used when large quantities of organic compounds are found in waste water. It originates from domestic sewage, urban run-off; industrial effluents and agriculture wastewater. Water shortage and water quality are the main issues in the global water crisis. As the population increases, there is ever growing demand on water resources. Wastewater with organic pollutants...

This study describes the photochemical deposition of Co-based oxygen evolution catalysts on a semiconductor photoanode for use in solar oxygen evolution. In the photodeposition process, electron-hole pairs are generated in a semiconductor upon illumination and the photogenerated holes are used to oxidize Co(2+) ions to Co(3+) ions, resulting in the precipitation of Co(3+)-based catalysts on the...

Heterobifunctional linker allows for selective catalyst-free ligation of two different azide-tagged substrates via strained-promoted azide-alkyne cycloaddition (SPAAC). The linker contains an azadibenzocyclooctyne (ADIBO) moiety on one end and a cyclopropenone-masked dibenzocyclooctyne (photo-DIBO) group on the other. The first azide-derivatized substrate reacts only at the ADIBO end of the lin...

Catalysts play a significant role in clean renewable hydrogen fuel generation through water splitting reaction as the surface of most semiconductors proper for water splitting has poor performance for hydrogen gas evolution. The catalytic performance strongly depends on the atomic arrangement at the surface, which necessitates the correlation of the surface structure to the catalytic activity i...

This paper remarks the general correlations of the shape and crystallinity of titanium dioxide (TiO₂) support on gold deposition and carbon monoxide (CO) oxidation. It was found that due to the larger rutile TiO₂ particles and thus the pore volume, the deposited gold particles tended to agglomerate, resulting in smaller catalyst surface area and limited gold loading, whilst anatase TiO₂ enabled...

Photocatalytic reduction of carbon dioxide has been investigated on three different titania catalysts (two commercial titania, De Gussa P-25 and UV-100 Hombikat and another catalyst prepared by sol-gel method under reverse micelle environment) dispersed in aqueous alkaline medium under irradiation in visible region (300-700 nm) from Hg lamp. The catalysts have been characterized by XRD, diffuse...

Water pollution by organic pollutants has been a growing global problem in recent years, for which there is a great demand of efficient technologies for wastewater treatment. Remediation of water by photocatalytic oxidation has several advantages over adsorption or any other conventional techniques. This study reports a easy synthesis technique of a sulfur doped hollow TiO2 nanocatalyst for pho...

Polydimethylsiloxane (PDMS) has been synthesized by ring-opening polymerization of octamethylcyclotetrasiloxane (D4) in microemulsion with acidic catalyst. The structure and properties of microemulsion were characterized by Transmission Electron Microscopy (TEM), Fourier Transform Infrared Spectroscopy (FT-IR), Photo Correlation Spectroscopy (PCS). The effect of the variation in pH value, amoun...