a simple, inexpensive and efficient method was used for extraction and determination of fexofenadine and levocetirizine with three–phase hollow fiber liquid-phase microextraction and high-performance liquid chromatography. several parameters influencing the extraction recoveries such as the nature of organic extraction solvent, ph of donor and acceptor phases, stirring rate, extraction time and...

The development of faster, simpler, inexpensive and more environmentally-friendly sample-preparation techniques is an important issue in chemical analysis. Recent research trends involve miniaturization of the traditional liquid-liquid-extraction principle by greatly reducing the acceptor-to-donor ratio. The current trend is towards simplification and miniaturization of sample preparation and d...

dracocephalum kotschyi (lamiaceae), as one of the remarkable aromatic plants, widely grows and also is cultivated in various temperate regions of iran. there are diverse reports about the composition of the oil of this plant representing limonene derivatives as its major compounds. there is no report on cloning of mono- or sesquiterpene synthases from this plant. in the present study, the aroma...

Aroma composition is critical to the quality of rice wine. In order clarify effect different koji on aroma components The Yuanyang was selected as raw material, and three kinds wine were added during fermentation. samples fermented at 31 °C for nine days qualitatively quantitatively analyzed by headspace solid-phase microextraction gas chromatography-mass spectrometry (HS-SPME-GC-MS). results s...

a simple and rapid microextraction procedure based on the application of magnetic nanoparticles and hydrophobic 1-hexylpyridinium hexafluorophosphate [hpy][pf6] ionic liquid (il) was applied to trace determination of gatifloxacin. a mixture of [hpy][pf6] and magnetic nanoparticles was injected into the sample solution containing the analyse of interest and a cloudy solution was formed. after ce...

Background & Aim:Nepeta racemosa is an herbal and medicinal plant and this report aims to   identify chemical compositions of the essential oils and volatiles of its   aerial parts through classical and advanced methods.  Experimental: Chemical profiles of the essential oils and volatile compounds from the aerial parts of Nepeta racemosa obtai...

Analyses of key odorous polyfunctional volatile thiols in wines (3-mercaptohexanol (3-MH), 3-mercaptohexylacetate (3-MHA), and 4-mercapto-4-methyl-2-pentanone (4-MMP)) are challenging due to their high reactivity and ultra-trace concentrations, especially when using conventional gas-chromatography electron impact mass spectrometry (GC-EI-MS). We describe a method in which thiols are converted t...

Grazing-exit x-ray fluorescence (GE-XRF) and micro x-ray fluorescence (micro-XRF) methods were applied to chemical microchips as a detection method. Since an energy-dispersive x-ray detector was used, the simultaneous detection of multiple elements was possible. An analyzing region was especially designed on the microchip so that a sample solution could be dried and concentrated in a suitable a...

In this study, hollow fiber liquid phase microextraction (HF-LPME) coupled with highperformanceliquid chromatography (HPLC) with UV detection was applied for preconcentrationand determination of Diclofenac sodium in biological fluids. Parameters affecting the extractionprocess including pH of donor phase and acceptor phase, type of extraction solvent, stirring rate,extraction time, and salt add...