In the present work, rapid identification of elements and their relative chemical composition in various Peganum harmala seed samples were investigated using a calibration-free laser-induced breakdown spectroscopy technique (CF-LIBS). A pulsed Nd:YAG laser-source with 5 ns pulse-duration, 10 Hz pulse repetition rates providing 400 200 mJ energy at 1064 532 nm wavelength, respectively, was focus...