Obtaining general relations between macroscopic properties of random assemblies, such as density, and the microscopic properties of their constituent particles, such as shape, is a foundational challenge in the study of amorphous materials. By leveraging existing understanding of the random packing of spherical particles, we estimate the random packing density for all sufficiently spherical sha...

Well-crystallized MSb(2)O(6) (M = Ca, Sr and Ba) powders synthesized by solid state reactions exhibit an interesting photocatalytic activity order of Ba > Sr > Ca for organic pollutant (methylene blue and phenol) degradation and hydrogen production from water under UV light irradiation. A simple model, crystal packing factor (PF), was introduced to account for the activity difference. Nine seri...

The dependence of structural self-organization of granular materials on preparation and grain parameters is key to predictive modeling. We study 60 different mechanically equilibrated polydisperse disc packs, generated numerically by two protocols. We show that, for same-variance disc size distributions (DSDs), (1) the mean coordination number of rattler-free packs versus the packing fraction i...

Based on first-principles calculations, the relationship between molecular packing and charge-transport parameters has been investigated and analysed in detail. It is found that the crystal packing forces in the flexible organic molecule 4-(1,2,2-triphenylvinyl)-aniline salicylaldehyde hydrazone (A) can apparently overcome the dynamic intramolecular rotations and the intramolecular steric repul...

In both nature and engineering, loosely packed granular materials are often compacted inside confined geometries. Here, we explore such behavior in a quasi-two dimensional geometry, where parallel rigid walls provide the confinement. We use the discrete element method to investigate the stress distribution developed within the granular packing as a result of compaction due to the displacement o...

Determination of sorption distribution coefficients (K(d)) of organic compounds by a dynamic soil column chromatography (SCC) method was developed and validated. Eurosoil 4, quartz, and alumina were chosen as exemplary packing materials. Heterocyclic aromatic compounds were selected in the validation of SCC. The prerequisites of SCC with regard to column dimension, packing procedure, and sample...

Dipolar colloidal particles self-assemble into a rich variety of microstructures ranging from co-crystals of unusual symmetry, to open networks (gels) of cross-linked chains of particles. We use molecular dynamics computer simulation to explore the self-assembly, structure, crystallization and/or gelation of systems of colloid particles with permanent dipole moments immersed in a high-dielectri...

Injection molding is one of the most common processes which are used for manufacturing different plastic parts. This method includes 3 continuous steps: filling of the mold, cooling and driving the part out. A wide range of plastic and Non-Plastic materials can be used as raw material in this process. One of the most important advantages of this way of production is that it is very economic. In...