نتایج جستجو برای: oxido

تعداد نتایج: 881  

Journal: :Acta Crystallographica Section E Structure Reports Online 2008

Journal: :Acta Crystallographica Section E Structure Reports Online 2011

Journal: :Zeitschrift für anorganische und allgemeine Chemie 2020

Journal: :Acta Crystallographica Section E Structure Reports Online 2011

2012
Guang-Chuan Ou Xian-You Yuan Zhi-Zhang Li

In the title compound, {[NiWO(4)(C(16)H(36)N(4))]·4H(2)O}(n), the Ni(II) ion lies on an inversion center and is octahedrally coordinated by four N atoms of the tetradentate macrocyclic 5,5,7,12,12,14-hexa-methyl-1,4,8,11-tetra-aza-cyclo-tetra-decane (L) ligand in the equatorial plane and two O atoms of [WO(4)](2-) anions in axial positions. Each [WO(4)](2-) anion bridges two adjacent [NiL](2+) ...

Journal: :Journal of the American Chemical Society 2013
Jacob S Kanady Jose L Mendoza-Cortes Emily Y Tsui Robert J Nielsen William A Goddard Theodor Agapie

The oxygen-evolving complex (OEC) of photosystem II contains a Mn(4)CaO(n) catalytic site, in which reactivity of bridging oxidos is fundamental to OEC function. We synthesized structurally relevant cuboidal Mn(3)MO(n) complexes (M = Mn, Ca, Sc; n = 3,4) to enable mechanistic studies of reactivity and incorporation of μ(3)-oxido moieties. We found that Mn(IV)(3)CaO(4) and Mn(IV)(3)ScO(4) were u...

Journal: :Zeitschrift für Naturforschung B 2022

Abstract Hydrothermal synthesis, crystal structure and properties of a new heterometallic coordination polymer [(VO(terpy)) 4 (MoO ) 2 (Mo 8 O 26 )]·2H ( 1 (terpy = 2,2′;6′,2″-terpyridine) are reported. Compound contains two crystallographically unique vanadium(IV) atoms, bonded to terminal oxido ligand further coordinated terpy ligand. The three N atoms occupy the meridional sites distorted {V...

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