a simple extremely fast and efficient approach for the synthesis of substituted indazole ingood to excellent yield catalyzed by using silica sulfuric acid (ssa) in dmso solvent at roomtemperature. this is solid state reaction have been attracting the synthetic organic chemist asthey provided enhance reaction rates, less environmental pollution, greater selectivity, cleanerproducts and manipulat...

Recently, studies on the construction of 3D terrain modeling and location accuracy evaluation using UAV have been conducted, but application to coastal areas lacking image matching points has not made in detail yet. In topography survey UAV, ortho-images DSM (Digital Surface Model) data were constructed through imaging ground control point (GCP) surveying ground. case ortho-images, VRS was used...

BACKGROUND The present study was conducted to evaluate the effect of different topical agents utilized for prevention of enamel decalcification around orthodontic brackets bonded to bleached and non-bleached enamel. METHODS Human maxillary premolars (n = 120) were divided into two equal groups. Teeth in group I were left without bleaching while those in group II were bleached with Vivastyle g...

Complex II inhibitors play an important role in agrochemical fungicide research and have been known for more than 40 years. With the introduction of ortho-substituted heterocyclic amides, a breakthrough in activity level and spectrum within this class was achieved. In the meantime all major agrochemical companies have entered this field. In this paper, a special complex II subclass, the pyrrole...

Reaction of ortho-carborane with anhydrous AlCl3 in chloroform results a mixture 9-chloro, 9,12-dichloro, and 8,9,12-trichloro derivatives 9,12-dichloro-ortho-carborane being the main product. Molecular crystal structure was determined by single X-ray diffraction. The 9,12-Cl2-1,2-C2B10H10 appeared to be nearly isostructural 9,12-dibromo-ortho-carborane: packing is built layers which molecules ...

A wavelength selective technique for light-induced network formation based on two photo-active moieties, namely ortho-methylbenzaldehyde and tetrazole is introduced. The network forming species are photo-reactive star polymers generated via reversible activation fragmentation chain transfer (RAFT) polymerization, allowing the network to be based on almost any vinylic monomer. Direct laser writi...

Aims. We report a detailed attempt to model the ortho-to-para abundance ratio of c-C3H2 so as to reproduce observed values in the cores of the well-known source TMC-1. According to observations, the ortho-to-para ratios vary, within large uncertainties, from a low of near unity to a high of approximately three depending on the core. Methods. We used the osu.2003 network of gas-phase chemical re...

Normal endocrine function in utero and early in childhood influences later height and weight attainment. Polychlorinated biphenyls (PCBs) are persistent environmental contaminants with suspected endocrine-disrupting properties. PCBs may mimic or inhibit hormone and endocrine processes based in part on their structural configuration, with non-ortho-substituted PCBs having a coplanar orientation ...

A concise synthesis of rubioncolin B is described, which features an unprecedented intramolecular Diels-Alder reaction involving an ortho-quinone methide and a naphthofuran moiety. The ortho-quinone methide is generated through a surprisingly facile tautomerization of a para-quinone.

Chiral aza-ortho-xylylene intermediates were efficiently generated from 3-chloro-3-substituted oxindole precursors. The first intramolecular trapping of chiral aza-ortho-xylylene intermediates led to a highly asymmetric synthesis of 3-spirocyclopropyl-2-oxindoles.