objective: adverse surface interactions between one-bottle adhesives and chemical-cured composites may occur with delayed light activation of light-cured composites. the purpose of this study was to assess the effects of delayed activation of light-cured composites on shear bond strength of two one-bottle adhesives with different acidity to bovine dentin. materials and methods: flat dentin surf...

The topological analysis of the gradient field of the electron localization function provides a convenient theoretical framework for the partition of the molecular space into basins of attractors having a clear chemical meaning. The basin populations are evaluated by integrating the one-electron density over the basins. The variance of the basin population provides a measure of the delocalizati...

Modern gas turbine hot sections need to be protected from elevated temperature and damaging environments. This protection starts as a typically two layer coating system, the base layer or bond coat (BC) acts as a corrosion barrier and a kind of buffer for the thermal mismatch between the base material and the second top thermally protective layer or Thermal Barrier Coating (TBC). The BC is norm...

Synthetic oligoribonucleotides have been used to probe the interaction of MS2 coat protein with the translational operator of the MS2 replicase gene. We have investigated the possible formation of a transient covalent bond between the single-stranded uridine residue, at position -5, and a cysteine side-chain on the coat protein, by the incorporation of a chemically modified residue (5-BrU) at t...

Coat protein complex II (COPII) mediates formation of the membrane vesicles that export newly synthesised proteins from the endoplasmic reticulum. The inner COPII proteins bind to cargo and membrane, linking them to the outer COPII components that form a cage around the vesicle. Regulated flexibility in coat architecture is essential for transport of a variety of differently sized cargoes, but ...

Stress development is one of the significant factors leading to the failure of thermal barrier coating (TBC) systems. In this work, stress development in the two phase mixed zone named phase transition layer (PTL), which grows between the thermally grown oxide (TGO) and the bond coat (BC), is investigated by using two different homogenization models. A constitutive equation of the PTL based on ...

A new interface fracture test was developed for ceramic environmental barrier coatings (EBCs) on matrix composites (CMCs). The proposed modifies an existing in order to simplify specimen preparation. An asymmetric double cantilever beam (ADCB) with a stiffener adhering the coating used, and wedge inserted into notch open it. formula calculate toughness using opening load displacement derived; i...