Here we demonstrate an approach to enhance the growth of vertically aligned carbon nanotubes (CNTs) by including a catalyst reservoir underneath the thin-film alumina catalyst underlayer. This reservoir led to enhanced CNT growth due to the migration of catalytic material from below the underlayer up to the surface through alumina pinholes during processing. This led to the formation of large F...

Abstraet--Jordanian natural kaolin and bentonite show good catalytic activity towards debutylating 2tert-butylphenol, and varying debutylation vs. isomerization selectivity after acid activation. The resulting catalytic activity of these samples is dependent on the acid employed for activation; the samples treated with acetic acid showed relatively low conversions, whereas those treated with hy...

The selective hydrogenation of dimedone (1) to the corresponding monoketone 2 over palladium and Amberlyst 15 ® is reported. The product is a synthetic building block for the fragrance and pharmaceutical industry. Advantages of the new catalytic procedure are the high catalyst activity and selectivity, less by-product formation, avoidance of the presence of acid, and consequently, less salt for...

The effect of transition metal doping on Pt/Al2O3 catalyst used in propane dehydrogenation reaction at 500 ̊C was studied. The preparation methods investigated were sequential impregnation (Pt followed by the 2 metal or the 2 metal followed by Pt) and co-impregnation. The metal contents of these catalysts were fixed as the weight ratio of Pt per the 2 metal of around 0.075. These catalysts were ...

This paper presents the performance studies of ATM via satellite based on experiments implemented by the RACE II CATALYST project R2074. The purpose of the project was to develop an ATM satellite link for the future B-ISDN services, particularly for the interconnections of the ATM testbeds which are in the form of broadband islands. Then initial ATM based B-ISDN can be introduced by interconnec...

Internal Gravity Waves (IGW) span time scales between the inertial frequency f (∼1 day−1) and buoyancy frequency N (∼15 min−1 in the thermocline). The level of the continuum (defined as all frequencies apart from near-inertial and tidal) is related to small scale mixing, but its energy sources are poorly understood. We hypothesize that the continuum receives energy only from the wind, the tides...

Two high-spin pentanuclear NiW clusters with diimine blocking ligands have been obtained: {[Ni(4,4'-MeObpy)2]3[W(CN)8]2}·12H2O (1) and {[Ni(phen)2(H2O)][Ni(phen)2]2[W(CN)8]2}·7H2O (2) (4,4'-MeObpy = 4,4'-dimethoxy-2,2'-bipyridine, phen = 1,10-phenanthroline). Despite the similarity of the building blocks and synthetic conditions the compounds show different topologies of the cluster core: 1 is ...

In most eukaryotic cells, entry Into mitosis is tightly controlled and requires completely replicated and undamaged DNA. We show that the antitumor drug, fostriecin, interferes with this control; it induces cycling cells to enter mitosis prematurely, and it can overcome the mitotic entry checkpoint, forcing into mitosis cells that were arrested in the division cycle by treatment with the DNA re...

palladium is the best metal catalyst for suzuki cross coupling reaction for synthesize of unsymmetrical biaryl compounds. but its high cost limits its application in wide scale. using of nanoscale particles as active catalytic cites is a good approach for reducing needed noble metal. by loading precious nanoparticles on magnetic nanocores as a support, recycling and reusing of catalyst will be ...

Effect of nitrogen post-doping on a commercial platinum–ruthenium/carbon anode catalyst Report Title This work investigates the effects of after-the-fact chemical modification of a state-of-the-art commercial carbonsupported PtRu catalyst for direct methanol fuel cells (DMFCs). A commercial PtRu/C (JM HiSPEC-10000) catalyst is post-doped with nitrogen by ion-implantation, where “post-doped” den...