The inverse method is a numerical method for fast estimation of adsorption isotherm parameters directly from a few overloaded elution profiles and it was recently extended to adsorption isotherm acquisition in gradient elution conditions. However, the inverse method in gradient elution is cumbersome due to the complex adsorption isotherm models found in gradient elution. In this case, physicoch...

A new chelating matrix, SiNP, has been prepared by immobilizing 1.5-dimethyl-1H-pyrazole-3-carbaldehyde on silica gel modified with 3-aminopropyl-trimethoxysilane. This new chelating material was well characterized by elemental analysis, FT-IR spectroscopy, cross polarization magic angle spinning solid state 13C-NMR, nitrogen adsorption-desorption isotherm, BET surface area, BJH pore size, and ...

A simple additive-free approach is developed to synthesize uniform manganese monoxide (MnO) one-dimensional nanorods, in which only manganese acetate and ethanol were used as reactants. The as-synthesized MnO nanorods were characterized in detail by X-ray diffraction, scanning and transmission electron microscopy (TEM) including high-resolution TEM and selected-area electron diffraction, Fourie...

Nanoconfined synthesized crystalline fullerene mesoporous carbon (C60-FMC) with bimodal pore architectures of 4.95 nm and 10-15 nm pore sizes characterized by XRD, TEM, nitrogen adsorption/ desorption isotherm and solid-state NMR, and the material was used for protein immobilization. The solid-state 13C NMR spectrum of C60-FMC along with XRD, BET and TEM confirms the formation of fullerene meso...

Isotherm equation is one of the important scientific bases for adsorbent selection. There are different isotherms that do not account for an adsorbate, different chemisorption geometries on the nanoporous surface. It is interesting to introduce a general isotherm, which considers different chemisorption geometries of an adsorbate on nanoporous surfaces. In this study, an isotherm for non-dissoci...

In this study Ceramium virgatum has been characterized and used for the removal of cadmium and lead from aqueous solutions. The effect of pH, adsorbent dosage, contact time and temperature on adsorption process was studied in batch experiments. Langmuir and Freundlich models were applied to describe the biosorption isotherm of the metal ions by C. virgatum biomass. The adsorption data can be we...

Activated carbon prepared from coir pith (ZnCPC) using ZnCl2 was investigated to find the feasibility of its application for removal of 2,4–dichlorophenol (2,4-DCP) in aqueous solution through adsorption process. Batch mode kinetics and isotherm studies were carried out to evaluate the effects of contact time, initial concentration, adsorbent dose, pH, and temperature. Lagergren, Second order, ...

The adsorption of Triton X-100 in aqueous solution on the granite sand has been investigated to evaluate its ability as an adsorbent. Various parameters such as agitation time, adsorbent dose, adsorbent size, initial concentration of adsorbate, pH, temperature, and effect of interference ions were studied on the laboratory scale to establish optimum conditions for the removal of TX-100 from the...

Biosorption is a process, which represents a biotechnological innovation as well as a cost effective excellent tool for removing heavy metals from aqueous solutions. The kinetics and equilibrium of the biosorption of Chromium (VI) from aqueous solution were investigated using immobilized mixed biosorbents of Annona squamosa seeds and Aspergillus niger in a batch system. The biosorption characte...

The adsorption of contaminants plays an important role in the process of their elimination from a polluted environment. This work describes the issue of loading environment with lead Pb(II) and the resulting negative impact it has on plants and living organisms. It also focuses on bentonite as a natural adsorbent and on the adsorption process of Pb(II) ions on the mixture of bentonite and botto...