CO2 and/or H2O were reduced to CO/H2 in micro-tubular solid oxide electrolysers with yttria-stabilized zirconia (YSZ) electrolyte, Ni-YSZ cermet cathode and strontium(II)-doped lanthanum manganite (LSM) oxygen-evolving anode. At 822 C, the kinetics of CO2 reduction were slower (ca. 0.49 A cm 2 at 1.8 V) than H2O reduction or co-reduction of CO2 and H2O, which were comparable (ca. 0.83 to 0.77 A...

Interpenetrating Al O /Al composites were created by liquid metal infiltration of alumina structures with three-dimensional periodicity produced by a robotic deposition method. Volume-averaged lattice strains in the alumina phase were measured by synchrotron X-ray diffraction at various uniaxial compression stresses up to 200 MPa. Load transfer was observed to occur from the aluminum to the alu...

Simple nanoporous alumina matrix modification procedure, in which the electrically highly insulating alumina barrier layer at the bottom of the pores is replaced with the conductive layer of the gold beds, was described. This modification makes possible the direct electron exchange between the underlying aluminum support and the redox species encapsulated in the alumina pores, thus, providing t...

BACKGROUND Numerous studies have reported that microgrooves on metal and polymer materials can affect cell adhesion, proliferation, differentiation and guidance. However, our knowledge of the cell activity associated with microgrooves on ceramics, such as alumina, zirconia, hydroxyapatite and etc, is very incomplete, owing to difficulties in the engraving of microgrooves on the hard surface of ...

Lanthanide (Ln3+) doping in alumina has shown great promise for stabilizing and promoting desirable phase formation to achieve optimized physical and chemical properties. However, doping alumina with Ln elements is generally accompanied by formation of new phases (i.e. LnAlO3, Ln2O3), and therefore inclusion of Ln-doping mechanisms for phase stabilization of the alumina lattice is indispensable...

This paper considers the degradation of alumina and zirconia toughened alumina vs. alumina for hip implants. The materials are as assumed to be load bearing surfaces subjected to shocks in wet conditions. The load is a peak of force; 9 kN was applied over 15 ms at 2 Hz for 800,000 cycles. The volumetric wear and roughness are lower for ZTA than for alumina. The long ZTA ageing did not seem to h...

Electrochemical processing is a cost effective and low-temperature approach suitable for the fabrication of certain unique nanostructures that are difficult to obtain by other methods. Here we report on the synthesis of nanowires and nanoporous structures with the intention to control the magnetic properties of conventional materials. Nanowires with variable sizes (diameter 15 nm microns, and l...

The use of the power and energy functional in the analysis of the electric circuits makes it possible to appreciate the energetic equilibrium state attained in the circuit at a certain moment. This paper is concerned with a demonstration of the principle of minimum dissipated active power for the steady state circuits under nonsinusoidal conditions. It is shown that the equilibrium state is one...

Anodic porous alumina has been widely investigated and used as a nanostructure template in various nanoapplications. The porous structure consists of numerous hexagonal cells perpendicular to the aluminum substrate and each cell has several tens or hundreds of nanoscale pores at its center. Because the nanomorphology of anodic porous alumina is limited by the electrolyte during anodizing, the d...

Experimental researches on adsorptive capacity of activated alumina, silica sand and anthracite coal for phosphorus were conducted. Results showed that performances of three filter media were all in line with Langmuir isotherm, and activated alumina adsorptive performance was much better than silica sand and anthracite coal for phosphorus removal. The adsorptive capacity of activated alumina, s...