In this work, a flow injection analysis (FIA) method for the trace determination of lead, cadmium, nickel and cobalt in natural waters by formation of neutral chelates with ammonium pyrrolidine dithiocarbamate (APDC) was developed. The neutral chelates formed was retained in a mini-column packed with Linde type A zeolite (LTA) and type Y Faujasite zeolite (FAU) and then eluted with methyl isobu...

Zeolite 13X molecular sieve with high sorption capacity and significant rate has been considered a promising candidate for seasonal heat storage. In this study, code is developed to simulate the adsorption process between zeolite water in all ranges of partial pressures, temperatures, sorbate loadings. The results from proposed were compared experiments good agreement was observed. After valida...

Mesoporous aggregates of nanocrystalline zeolites with MFI and BEA frameworks have been synthesized using a one-pot and single structure directing agent. The effect of different reaction conditions, such as temperature, time, pH and water content, on the particle size, surface area and mesopore volume has been studied. Nanocrystalline and mesoporous ZSM-5, β and Y zeolites were modified with di...

Faujasite (FAU) zeolites (with Si/Al ratio of ca. 1.7) undergo mild dealumination at moderate ion exchange conditions (0.01 to 0.6 M NH4NO3 solutions) resulting in protons circumscribed by sodalite cages becoming accessible for reaction without conspicuous changes bulk crystallinity. The (HSOD) supercages (HSUP) can be systematically manipulated from 0 1 adjusting ammonium concentrations used e...

Thermal decomposition in a thermobalance of Fe(CO), adsorbed on alkali-metal, hydrogen-Y, dealuminated Y, L and omega zeolites proceeds stepwise via slow decarbonylation at low and high temperatures, separated by a fast endothermic reaction. Average CO/Fe ratios have been determined after each step. From i.r. results the former intermediates are assigned to species bearing bridging CO, whereas ...