Two power plant schemes that reduce CO2 emission and employ natural gas reforming were analyzed and discussed. The first one integrates natural gas reforming technology for efficiency improvement with an oxy-fuel combined power system (OXYF-REF), with water as the main work fluid. The reforming heat is obtained from the available turbine exhaust heat, and the produced syngas is used as fuel wit...

The intrinsic kinetics and diffusion behaviour of methane steam reforming have been investigated in this work. Measurements of effective diffusivities of the gases present in methane steam reforming have been carried out by using the steady-state technique over wide ranges of temperature and pressure in a modified Wicke-Kallenbach (W-K) type diffusion apparatus. The effects of diffusion limitat...

Photocatalytic water splitting and organic reforming based on nano-sized composites are gaining increasing interest due to the possibility of generating hydrogen by employing solar energy with low environmental impact. Although great efforts in developing materials ensuring high specific photoactivity have been recently recorded in the literature survey, the solar-to-hydrogen energy conversion ...

10-membered ring IM-5 zeolite has shown excellent performance in many catalytic reactions. The efficient preparation of high silica by situ synthesis remains huge challenge. Here, with SiO2/Al2O3 ratio (SAR) 49–116 was acquired HNO3 treatment. An interesting stepwise dealumination behavior discovered during the whole acid-treatment process (based on XRF characterization). Extra-framework Si (EF...

Currently, hydrogen is mainly produced through steam reforming of natural gas. However, this conventional process involves environmental and energy security concerns. This has led to the development of alternative technologies for (potentially) green hydrogen production. In this work, the environmental and energy performance of biohydrogen produced in Europe via steam reforming of glycerol and ...

This paper presents the performance analysis of a planar solid-oxide fuel cell (SOFC) under direct internal reforming conditions. A detailed olid-oxide fuel cell model is used to study the influences of various operating parameters on cell performance. Significant differences in efficiency nd power density are observed for isothermal and adiabatic operational regimes. The influence of air numbe...

The aim of this work was the evaluation of the catalytic steam reforming of a gaseous fuel obtained by steam biomass gasification to convert topping atmosphere residue (TAR) and CH4 and to produce pure H2 by means of a CO2 sorbent. This experimental work deals with the demonstration of the practical feasibility of such concepts, using a real woodgas obtained from fluidized bed steam gasificatio...

Biodiesel’s contribution as a renewable energy carrier is increasing continuously. Fuel cell market penetration, although slow, is now an irreversible reality. The combination of solid oxide fuel cells (SOFC) with biodiesel offers considerable advantages because it entails both high energy conversion efficiency and nearzero atmospheric carbon emissions. This work is aimed at proving the efficie...

For the new process of effective utilization of energy, chemical recuperation of low-grade exhaust heat by steam reforming of dimethyl ether (DME) was proposed. Steam reforming of DME is an endothermic reaction as; DME + 3H2O + 122[kJ/mol] → 6H2 + 2CO2. If this reaction could be proceed by exhaust heat below 573 [K], those exhaust heat which is wasted to ambient would be recuperated as the fuel...

This paper documents the application of exhaust gas fuel reforming of two alternative fuels, biodiesel and bioethanol, in internal combustion engines. The exhaust gas fuel reforming process is a method of on-board production of hydrogen-rich gas by catalytic reaction of fuel and engine exhaust gas. The benefits of exhaust gas fuel reforming have been demonstrated by adding simulated reformed ga...